1311484-52-2

Basic information

• Product Name: MIDA alkenyl-2-boronate
• Synonyms: MIDA alkenyl-2-boronate
• CAS NO: 1311484-52-2
• Molecular Weight: 259.069
• Mol File: 1311484-52-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: MIDA alkenyl-2-boronate(CAS DataBase Reference)
• NIST Chemistry Reference: MIDA alkenyl-2-boronate(1311484-52-2)
• EPA Substance Registry System: MIDA alkenyl-2-boronate(1311484-52-2)

Safety Data

• Hazardous Substances Data: 1311484-52-2(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 4408-64-4 N-methyliminodiacetic acid 
• 1104636-73-8 6-methyl-2-vinyl-1,3,6,2-dioxazaborocane-4,8-dione 
• 1449377-16-5 C₇H₉BBrNO₄ 
• 98-80-6 phenylboronic acid 

Downstream Products

• 87324-13-8 1-(4-(1-phenylvinyl)phenyl)ethanone 
• 1414852-68-8 2-benzoyl-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione 
• 35342-69-9 2-phenyl-1,4-pentadiene 
• 119-61-9 benzophenone 
• 92674-40-3 phenyl(pyrimidin-5-yl)methanone 
• 21221-93-2 [3,5-bis(trifluoromethyl)phenyl](phenyl)methanone 
• 1503-49-7 p-cyanobenzophenone 
• 15165-27-2 ethyl 4-benzoylbenzoate 
• 53689-84-2 4-acetylbenzophenone 
• 1144-74-7 4-nitrobenzophenone 
• 345-83-5 4-fluorobenzophenone 
• 530-44-9 4-(Dimethylamino)benzophenone 
• 611-94-9 4-Methoxybenzophenone 
• 134-84-9 4-Methylbenzophenone 

Relevant articles and documents

Synthesis, Structure and Reactivities of Pentacoordinated Phosphorus–Boron Bonded Compounds

The isolation and reactivities of two pentacoordinated phosphorus–tetracoordinated boron bonded compounds were explored. A highly Lewis acidic boron reagent and electron-withdrawing ligand system were required to form the pentacoordinated phosphorus state of the P–B bond. The first compound, a phosphoranyl-trihydroborate, gave a THF stabilised phosphoranyl-borane intermediate upon a single hydride abstraction in THF. This compound could undergo a unique rearrangement, which involved a two-fold ring expansion, to give a fused bicyclic compound or it could act as a mono-hydroboration reagent. The hydroboration reactivity of the intermediate was found to be higher towards alkynes vs. alkenes, with good to moderate regioselectivity towards the terminal carbon. The second compound, a phosphoranyl-triarylborate, was found to have different reactivity as it was highly stable towards acids and bases. This is thought to be due to the large bulk around the P–B bond as shown in the crystal structure.