131214-87-4

Basic information

• Product Name: 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato copper(II)
• Synonyms: 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato copper(II)
• CAS NO: 131214-87-4
• Molecular Weight: 1307.45
• Mol File: 131214-87-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato copper(II)(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato copper(II)(131214-87-4)
• EPA Substance Registry System: 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato copper(II)(131214-87-4)

Safety Data

• Hazardous Substances Data: 131214-87-4(Hazardous Substances Data)

Upstream product

• 185502-78-7 cadmium 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinate 
• 142-71-2 copper diacetate 
• 128-08-5 N-Bromosuccinimide 
• 14172-91-9 (tetraphenylporphyrin)copper(II) 
• 14977-07-2 5,10,15,20-tetraphenylporphyrinato cadmium(II) 
• 917-23-7 5,15,10,20-tetraphenylporphyrin 
• 7726-95-6 bromine 
• 6046-93-1 copper(II) acetate monohydrate 

Downstream Products

• 131214-88-5 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato zinc(II) 

Relevant articles and documents

Synthesis of β-Bromo-Substituted Cu(II) Tetraphenylporphyrinates

Bromination reactions of Cu(II) 5,10,15,20-tetraphenylporphyrinate with N-bromosuccinimide in chloroform and chloroform–dimethylformamide mixture and complexation of 2-bromo-5,10,15,20-tetraphenylporphyrin and 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin with copper(II) acetate in dimethylformamide have been studied. Mono-, tetra-, and octabromo-substituted Cu(II) porphyrinates have been synthesized. Obtained compounds have been identified by electronic absorption spectroscopy, IR spectroscopy, mass spectrometry, and elemental analysis.

Kinetics and mechanism of metal exchange between cadmium porphyrin complexes and d-metal salts in DMF

The metal-exchange reaction between cadmium 2,3,7,8,12,13,17,18-octabromo- 5,10,15,20-tetraphenylporphyrinate and zinc and copper acetates in DMF was studied. Kinetic Parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.

Complex formation of β-brominated tetraphenylporphyrins and metal exchange of their cadmium complexes with d-metal salts in dimethylformamide

Complex formation of zinc and copper(II) acetates with tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, and 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in N,N-dimethylformamide has been studied. The rate constants determined in the study of the complex formation and the metal exchange reactions have been compared.