1313878-07-7

Basic information

• Product Name: (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl acetate
• Synonyms: (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl acetate
• CAS NO: 1313878-07-7
• Molecular Weight: 302.178
• Mol File: 1313878-07-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl acetate(1313878-07-7)
• EPA Substance Registry System: (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl acetate(1313878-07-7)

Safety Data

• Hazardous Substances Data: 1313878-07-7(Hazardous Substances Data)

Upstream product

• 1138162-59-0 C₁₈H₂₉BO₃Si 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 167896-49-3 (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-2-en-1-ol 
• 108-24-7 acetic anhydride 
• 100-52-7 benzaldehyde 
• 118665-81-9 trimethyl((1-phenylprop-2-yn-1-yl)oxy)silane 

Downstream Products

• 1313878-34-0 (E)-2-[1-phenyl-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)allyl]malonic acid dimethyl ester 
• 119793-72-5 (E)-2-(3-phenyl-allyl) malonic acid dimethyl ester 
• 1313878-40-8 (E)-2-(1-phenyl-3-(p-tolyl)allyl)malonic acid dimethyl ester 

Relevant articles and documents

Synthesis of (Z)-alkene-containing linear conjugated dienyl homoallylic alcohols by a palladium-catalyzed three-component reaction

A synthesis of (Z)-alkene-containing linear conjugated dienyl homoallylic alcohols by using a palladium-catalyzed three-component reaction has been developed. This method shows good functional-group compatibility and generality, with high diastereoselectivity. Additionally, in many cases, the present method controls the alkene stereochemistry of the newly formed C-C bond and overcomes the inherent preference for (E)-alkene formation, giving (Z, E)- and (Z, Z)-products.