900783-31-5

Upstream product

• 128990-14-7 (S)-2-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-hydroxyethyl4-methylbenzenesufonate 
• 84379-53-3 2-O-benzyl-3,4-O-isopropylidene-L-threitol 
• 693-25-4 n-pentylmagnesium bromide 
• 131446-96-3 (S)-2-(benzyloxy)-2-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethyl 4-methylbenzenesulfonate 
• 91274-05-4 (2S,3S)-1,2-O-isopropylidene-1,2,3,4-tetrol 
• 93367-10-3 (2S,3S)-3,4-epoxy-1,2-di-O-isopropylidenebutane-1,2-diol 
• 110-53-2 1-Bromopentane 
• 100-39-0 benzyl bromide 
• 143707-07-7 1-[2,2-dimethyl-(4S)-1,3-dioxolan-4-yl]-(1S)-heptan-1-ol 

Downstream Products

• 900783-32-6 (2S,3S)-3-(benzyloxy)nonane-1,2-diol 

Relevant academic research and scientific papers

Enantiodivergent total synthesis of microcarpalide from l-tartaric acid

Stereoselective approach for the synthesis of both enantiomers of bio-active decanolactone microcarpalide is described from l-tartaric acid. The synthesis of the key intermediates en route to the natural product is achieved from l-tartaric acid involving

Stereoselective total synthesis of microcarpalide

A stereoselective total synthesis of microcarpalide using ring-closing metathesis (RCM) as a key step is reported. l-Ascorbic acid was used as a chiral pool material for the construction of the olefinic alcohol and an asymmetric aldol reaction provided the chiral precursor for the synthesis of olefinic acid.