13165-68-9

Basic information

• Product Name: N-Sulfinyl-4-chlorobenzenamine
• Synonyms: 4-Chloro-N-sulfinylaniline;N-Sulfinyl-4-chlorobenzenamine;1-chloro-4-(sulfinylamino)benzene
• CAS NO: 13165-68-9
• Molecular Formula: C₆H₄ClNOS
• Molecular Weight: 173.62
• Mol File: 13165-68-9.mol
• Article Data: 11

Chemical Properties

• Melting Point: 36 °C(Solv: carbon tetrachloride (56-23-5))
• Boiling Point: 247°Cat760mmHg
• Flash Point: 103.2°C
• Appearance: /
• Density: 1.37g/cm³
• Vapor Pressure: 0.0413mmHg at 25°C
• Refractive Index: 1.613
• CAS DataBase Reference: N-Sulfinyl-4-chlorobenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Sulfinyl-4-chlorobenzenamine(13165-68-9)
• EPA Substance Registry System: N-Sulfinyl-4-chlorobenzenamine(13165-68-9)

Safety Data

• Hazardous Substances Data: 13165-68-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H4ClNOS/c7-5-1-3-6(4-2-5)8-10-9/h1-4H

Upstream product

• 106-47-8 4-chloro-aniline 
• 76541-52-1 N-(chlorosulfinyl)imidazole 
• 3005-50-3 N,N'-Thionyldiimidazole 
• 88693-68-9 trichloro-methanesulfenic acid-(4-chloro-anilide) 
• 119151-47-2 Trichlormethansulfinsaeure-<4-chlor-anilid> 
• 63911-86-4 (4-Chloro-phenyl)-trimethylsilanyl-amine 

Downstream Products

• 13633-74-4 3-(4-chloro-phenyl)-[1,2,3]oxathiazolidine 2-oxide 
• 20447-60-3 7-(4-chloro-phenyl)-3,3-dimethyl-8-thia-2,7-diaza-bicyclo[4.2.0]oct-1⁽⁶⁾-ene 8-oxide 
• 5044-44-0 2-(p-chlorophenyl)-3,6-dihydro-1,2-thiazine 1-oxide 
• 139286-16-1 (E)-p-tolylethylenylsulphin-p-chloroanilide 
• 139286-18-3 (E)-p-chlorophenylethylenylsulphin-p-chloroanilide 
• 139286-15-0 diphenylethylenylsulphin-p-chloroanilide 
• 139286-20-7 (Z)-p-methoxyphenylethylenylsulphin-p-chloroanilide 
• 139286-17-2 (E)-p-methoxyphenylethylenylsulphin-p-chloroanilide 
• 13463-40-6 iron pentacarbonyl 
• 52500-74-0 tricarbonyl bis(tri-p-tolylphosphine) iron 
• 52278-75-8 (CO)4FeP(C₆H₄CH₃-p)3 
• 85134-88-9 [Fe(P(4-MeC₆H₄)3)2(CO)2(4-ClC₆H₄NSO)] 
• 1344679-91-9 (1R,4S)-N-(4-chlorophenyl)-4-ethyl-4-phenyl-1,2-thiazetidin-3-one 1-oxide 
• 1344679-90-8 (1S,4R)-N-(4-chlorophenyl)-4-ethyl-4-phenyl-1,2-thiazetidin-3-one 1-oxide 

Relevant articles and documents

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Synthesis of benzo-ortho-thiazines S-oxides by diels-alder reaction of N-sulfinylanilines with norbornadiene

From substituted N-sulfinylanilines acting as dienes in the Diels-Alder reaction with norbornadiene S-oxides of benzo-ortho-thiazines were obtained, which were oxidized into the corresponding S,S-dioxides belonging to the class of hybrid thiazinesulfonami

A-new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions.