132016-28-5

Basic information

• Product Name: methyl-(2-nitro-phenyl)-sulfoxide
• CAS NO: 132016-28-5
• Molecular Weight: 185.203
• Mol File: 132016-28-5.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: methyl-(2-nitro-phenyl)-sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-(2-nitro-phenyl)-sulfoxide(132016-28-5)
• EPA Substance Registry System: methyl-(2-nitro-phenyl)-sulfoxide(132016-28-5)

Safety Data

• Hazardous Substances Data: 132016-28-5(Hazardous Substances Data)

Upstream product

• 67-68-5 dimethyl sulfoxide 
• 88-74-4 2-nitro-aniline 
• 3058-47-7 methyl 2-nitrophenyl sulfide 
• 67-71-0 dimethylsulfone 
• 125556-93-6 2-(2-Nitro-benzenesulfinyl)-pyridine 1-oxide 
• 74-88-4 methyl iodide 

Downstream Products

• 824-39-5 sodium o-nitrophenate 
• 35540-02-4 C₇H₈N₂O₃S 

Relevant articles and documents

g-C3N4/H3PW4Mo8O40 S-scheme photocatalyst with enhanced photocatalytic oxidation of alcohols and sulfides

In this work, graphitic carbon nitride (g-C3N4) decorated with molybdenum-substituted tungstophosphoric acid as a novel photocatalyst (H3PW4Mo8O40/g-C3N4) was used to catalyze the oxidation of alcohols and sulfides. H3PW4Mo8O40/g-C3N4 (PW4Mo8/g-C3N4) displays higher photocatalytic activity under visible light irradiation for the oxidation of alcohols and sulfides compared with Keggin/g-C3N4 (PW12/g-C3N4). To obtain the optimum value, molybdenum substitution contents (H3PW12-xMoxO40) were changed from x = 4 to 12. The results showed that PW4Mo8 produces the best yield under visible-light irradiation. The results showed that PW4Mo8 was the best sample. The reaction rate increase can be due to the redox and acid properties of PW4Mo8/g-C3N4. This study provides a new insight for the preparation of highly efficient photocatalysts for the oxidation of organic compounds.

Aluminum(III) Chloride Promoted Oxygen Transfer: Selective Oxidation of Sulfides to Sulfoxides

An efficient selective oxidation of sulfides to sulfoxides has been developed by means of AlCl 3 -promoted oxygen transfer from phenyliodine diacetate [PhI(OAc) 2 ]. AlCl 3 proved to be the optimalLewis acid for the activation of PhI(OAc) 2. Various substituted sulfides were selectively transformed into the corresponding sulfoxides in good to excellent yields (≤99%). The high efficiency, excellent functional-group compatibility, broad substrate scope, and mild conditions render the current transformation useful for the synthesis of sulfoxides.

Oxidation of organic sulfides by imidazolium fluorochromate: A kinetic and mechanistic approach

The oxidation of organic sulfides by imidazolium fluorochromate resulted in the formation of the corresponding sulfoxides. The reaction is first order with respect to imidazolium fluorochromate. A Michaelis-Menten type kinetics was observed with respect t