132077-84-0

Basic information

• Product Name: (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene
• Synonyms: (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene
• CAS NO: 132077-84-0
• Molecular Weight: 180.247
• Mol File: 132077-84-0.mol

Chemical Properties

• CAS DataBase Reference: (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene(132077-84-0)
• EPA Substance Registry System: (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene(132077-84-0)

Safety Data

• Hazardous Substances Data: 132077-84-0(Hazardous Substances Data)

Upstream product

• 132042-13-8 (S)-(-)-1-Acetoxy-4-(1-acetoxy-1-methylethyl)-1-cyclohexene 
• 38651-65-9 (1R,5S)-(+)-nopinone 

Downstream Products

• 145747-47-3 ((S)-4-Isopropenyl-cyclohex-1-enyloxy)-trimethyl-silane 
• 132042-18-3 (R)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-3-furan-3-ylmethyl-4-isopropyl-2-phenylselanyl-cyclohexanol 
• 132042-17-2 (R)-3-Furan-3-ylmethyl-1-hydroxymethyl-4-isopropyl-2-phenylselanyl-cyclohexanol 
• 132060-16-3 ((R)-3-Furan-3-ylmethyl-4-isopropyl-cyclohex-1-enyl)-methanol 
• 95653-79-5 noroxopenlanfuran 
• 132042-15-0 (R)-4-Isopropyl-1-methylsulfanylmethyl-cyclohex-2-enol 
• 23963-66-8 (R)-6-Isopropyl-1-oxa-spiro[2.5]oct-4-ene 
• 145747-46-2 (S)-4-Isopropyl-2-phenylselanyl-cyclohexanone 
• 94597-61-2 (S)-(-)-4-isopropenyl-2-cyclohexen-1-one 
• 100190-37-2 (S)-4-iso-propyl-1-trimethylsilyloxy-1-cyclohexene 
• 2158-59-0 (R)-(-)-cryptone 
• 100295-52-1 (S)-(-)-4-isopropylcyclohex-2-enone 
• 132042-14-9 (S)-(-)-1-Acetoxy-4-isopropyl-1-cyclohexene 

Relevant articles and documents

Efficient and convenient syntheses of (R)-(-)-cryptone and (S)-(-)-isopropenyl-2-cyclohexen-1-one

Starting with (+)-nopinone (3); (R)-(-)-cryptone (1) and (S)(-)-4-isopropenyl-2-cyclohexen-1-one (2) were synthesized in five steps and 42% overall yield, and four steps and 49% overall yield, respectively.

Efficient Preparation of (R)-(-)-Cryptone form (+)-Nopinone and Its Transformation into Noroxopenlanfuran

Starting with (R)-(-)-cryptone, prepared in 42percent overall yield from (+)-nopinone in five steps, the first synthesis of noroxopenlanfuran was accomplished, confirming its absolute configuration.