145747-47-3

Basic information

• Product Name: 1-trimethylsilyloxy-4-isopropenyl-1-cyclohexene
• Synonyms: 1-trimethylsilyloxy-4-isopropenyl-1-cyclohexene
• CAS NO: 145747-47-3
• Molecular Weight: 210.392
• Mol File: 145747-47-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-trimethylsilyloxy-4-isopropenyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-trimethylsilyloxy-4-isopropenyl-1-cyclohexene(145747-47-3)
• EPA Substance Registry System: 1-trimethylsilyloxy-4-isopropenyl-1-cyclohexene(145747-47-3)

Safety Data

• Hazardous Substances Data: 145747-47-3(Hazardous Substances Data)

Upstream product

• 61692-28-2 1-<(Trimethylsilyl)oxy>-4-acetyl-1-cyclohexene 
• 19493-09-5 Methylenetriphenylphosphorane 
• 75-77-4 chloro-trimethyl-silane 
• 132077-84-0 (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene 
• 38651-65-9 (1R,5S)-(+)-nopinone 
• 132042-13-8 (S)-(-)-1-Acetoxy-4-(1-acetoxy-1-methylethyl)-1-cyclohexene 

Downstream Products

• 62702-87-8 (+/-)-4-isopropenyl-2-cyclohexen-1-one 
• 94597-61-2 (S)-(-)-4-isopropenyl-2-cyclohexen-1-one 
• 22460-53-3 4-isopropenylcyclohexanone 

Relevant articles and documents

Efficient and convenient syntheses of (R)-(-)-cryptone and (S)-(-)-isopropenyl-2-cyclohexen-1-one

Starting with (+)-nopinone (3); (R)-(-)-cryptone (1) and (S)(-)-4-isopropenyl-2-cyclohexen-1-one (2) were synthesized in five steps and 42% overall yield, and four steps and 49% overall yield, respectively.

Synthetic Approach to the Amphilectane Diterpenes: The Use of Nitriles as Terminators of Carbocation-Olefin Cyclizations

A biomimetic approach to the synthesis of tricyclic terpenoid isonitriles from marine sponges is described which involves carbocation-olefin cyclization of polyolefinic precursors terminated by the stereoselective formation of a carbon-nitrogen bond.The k