1322091-04-2Relevant academic research and scientific papers
An l-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions
Wu, Xiao,He, Cheng,Wu, Xiang,Qu, Siyi,Duan, Chunying
, p. 8415 - 8417 (2011)
A homochiral metal-organic triangle Co-Pro1 was achieved via self-assembly by incorporating a l-proline moiety within the corresponding ligand. Co-Pro1 comprised l-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked
V-shaped chiral carboxylic acid ligand, preparation method and application thereof
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Paragraph 0041; 0044, (2021/07/31)
The invention discloses a V-shaped chiral carboxylic acid ligand L-H2, relates to the technical field of synthetic chemistry and coordination chemistry, and also provides a preparation method of the ligand and an application of the ligand in assembling chiral complexes. The preparation method has the beneficial effects that the prepared V-shaped chiral carboxylic acid ligand is cheap in synthesis raw materials, simple in preparation method and suitable for large-scale preparation, has proper ligand rigidity and special coordination guidance and is beneficial to overcoming the flexibility of a framework of amino acid and the flexibility of a coordination mode. Therefore, a complex material with a chiral structure is easy to assemble.
