13225-54-2

Upstream product

• 498-66-8 norborn-2-ene 
• 70-55-3 toluene-4-sulfonamide 
• 127-65-1 chloroamine-T 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 1338062-05-7 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 
• 76152-15-3 N-iodo-N-potassio-p-toluenesulphonamide 
• 41085-71-6 bromamine T 
• 498-66-8 norbornene 

Relevant academic research and scientific papers

Control of the platinum(II) ligating properties of rigid 1,2-diamines: the case of trans-2,3-diaminonorbornane

Guided by a simple predictive model, a norbornane-based trans-1,2-diamine was identified as a potential bridging ligand for di-nuclear platinum complex formation; efficient synthesis and product characterization confirmed this hypothesis.

Bromamine-T: A superior source of nitrene for aziridination of olefins

Bromamine-T as a superior source of nitrene compared to Chloramine-T in the Cu-catalyzed aziridination of olefins is reported in this communication.

Syntheses of acetonitrile ligated copper complexes with perfluoroalkoxy aluminate as counter anion and their catalytic application for olefin aziridination

Acetonitrile ligated copper complexes with perfluoroalkoxy aluminate Al {OC (CF3)3}4- as weakly coordinating counter anion are successfully synthesized. Aziridination of various olefins with PhINTs catalyzed by

Synthesis, characterisation and reactivity of novel bis(tosyl)imidoruthenium(VI) porphyrin complexes; X-ray crystal structure of a tosylamidoruthenium(IV) porphyrin

Bis(tosyl)imidoruthenium(VI) porphyrin complexes are prepared and characterised by spectroscopic means; [RuVI-(tpp)(NTs)2] can undergo imido group transfer reactions with alkenes to afford aziridines, as well as C-H bond oxidation of

Nitrogen atom transfer to alkenes utilizing Chloramine-T as a nitrogen source

Aziridination of alkenes proceeds successfully using Chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide). When anhydrous Chloramine-T was added to an acetonitrile solution of alkenes in the presence of various CuCl catalysts and MS-5A, the corresponding

Functionalization of Alkenes through Telescoped Continuous Flow Aziridination Processes

Alkenes can be efficiently aziridinated using highly soluble iminoiodane derivatives under continuous flow conditions. By combining the aziridine generation with nucleophilic ring opening reactions, a variety of products can be made without the need to ha

Grafting of copper(II) Schiff base complex on functionalized multi-wall carbon nanotubes: Synthesis, characterization and catalytic aziridination of olefins

In this study, hydroxyl functionalized copper(II) Schiff-base; [Cu((OH)2-salophen)], [(OH)2-salophen] = (N,N-bis(4-hydroxysalicylidene) phenylene-1,2-diamine); has been covalently anchored on modified multi-wall carbon nanotubes (MWN

Half-sandwich scorpionates as nitrene transfer catalysts

Scorpionate complexes of the middle to late 3d transition metals [(L)M(NCMe)3](BF4)n (M = Mn, Fe, Co, Ni: 1 M, L = tris(3,5-dimethylpyrazol-1-yl)methane, TpmMe,Me, n = 2; 2M, L = tris(3-phenylpyrazol-1-yl)methane, TpmPh, n = 2; 3M except 3Mn, L = hydrotris(3,5-dimethylpyrazol-1-yl) borate, [TpMe,Me]-, n = 1; 4M, L = hydrotris(3-phenyl-5-methylpyrazol-1-yl)borate, [TpPh,Me] -, n = 1) were examined as catalysts for styrene aziridination and THF amination using phenyl-N-tosyliodinane as a nitrene donor. [(Tpm Me,Me)Fe(NCMe)3](BF4)2 (1 Fe) was identified as the most active catalyst, giving nearly quantitative nitrene transfer yields at 5 mol % loadings. The reactivity of 1Fe with a wider range of organic substrates was also explored, and a striking observation was strong selectivity for aromatic rather than benzylic amination for alkylaromatic substrates.

O-alkoxyphenyliminoiodanes: Highly efficient reagents for the catalytic aziridination of alkenes and the metal-free amination of organic substrates

Efficient nitrene precursors: Highly reactive iminoiodane-based nitrene precursors were prepared from ortho-alkoxyiodobenzenes. Owing to the presence of the ortho-substituent on the phenyl ring, these new iminoiodanes have excellent solubility in organic

Cu(acac)2 Immobilized in Ionic Liquids: A Novel and Recyclable Catalytic System for Aziridination of Olefins Using PhI=NTs as Nitrene Donor

Copper (II) acetylacetonate immobilized in ionic liquids efficiently catalyzes aziridination of olefins in good yields at a faster rate than the ealier reported methods using PhI=NTs as a nitrene donor with easy catalyst/solvent recycling.