132292-26-3

Basic information

• Product Name: 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal
• Synonyms: 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal
• CAS NO: 132292-26-3
• Molecular Weight: 366.498
• Mol File: 132292-26-3.mol

Chemical Properties

• CAS DataBase Reference: 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal(CAS DataBase Reference)
• NIST Chemistry Reference: 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal(132292-26-3)
• EPA Substance Registry System: 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal(132292-26-3)

Safety Data

• Hazardous Substances Data: 132292-26-3(Hazardous Substances Data)

Upstream product

• 66500-55-8 cyclohexanone-4-carboxylic acid ethyleneacetal 
• 92-68-2 4-cyclohexylcyclohexanone 

Downstream Products

• 132292-30-9 cis-1,1':4',1''-tercyclohexan-4-one 
• 132292-31-0 trans-1,1':4',1-tercyclohexyl-4-one 
• 132292-28-5 <1,1':4',1''-tercyclohex-1(2)-en>-4-one 
• 132292-29-6 <1,1':4',1''-tercyclohex-1'(2')-en>-4-one 
• 112649-02-2 4-[4-(cyclohexyl)cyclohexyliden]-1-cyclohexanone 
• 132292-27-4 4-(4'-cyclohexylcyclohexylidene)cyclohexanone ethylene ketal 

Relevant articles and documents

Synthesis of tercyclohexanones

A synthetic route to tercyclohexanones is described in which alkylation of 4-cyclohexylcyclohexanone with the dianion of 4,4-(ethylenedioxy)cyclohexanecarboxylic acid gives 1-carboxy-1'-hydroxyl-1,1':4',1''-tercyclohexan-4-one ethylene ketal. Decarboxylative dehydration of the latter followed by hydrolysis of the ketal gives 4-(4'-cyclohexylcyclohexylidene)cyclohexanone. Hydrogenation of this compound gives cis- and trans-1,1':4',1''-tecyclohexan-4-one, the latter of which is correlated with authentic trans-1,1':4',1''-tercyclohexane.