132375-84-9

Upstream product

• 132375-83-8 (2R,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,3-bis-ethylsulfanyl-decahydro-1,8,10-trioxa-anthracene 
• 221381-08-4 (4aR,5aS,6aR,8S,10S,10aS,11aR,12aS)-10-Benzyloxy-2,2-dimethyl-dodecahydro-1,3,5,7,11-pentaoxa-naphthacene-8-carbaldehyde 
• 100-39-0 benzyl bromide 
• 132375-82-7 (2R,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-octahydro-1,8,10-trioxa-anthracen-3-one 
• 75-08-1 ethanethiol 
• 132375-80-5 (2R,3S,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-decahydro-1,8,10-trioxa-anthracen-3-ol 
• 132375-81-6 (2R,3S,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-hydroxymethyl-decahydro-1,8,10-trioxa-anthracen-3-ol 
• 122821-81-2 2,6-Anhydro-1-O-(tert-butyldiphenylsilyl)-3,7,8,9-tetradeoxy-4,5-O-isopropylidene-D-altro-non-8-enitol 
• 132375-76-9 (E)-3-((2S,3S)-3-{(3S,4aR,6R,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-octahydro-pyrano[3,2-b]pyran-2-ylmethyl}-oxiranyl)-acrylic acid methyl ester 
• 132375-73-6 (E)-4-{(3S,4aR,6R,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-octahydro-pyrano[3,2-b]pyran-2-yl}-but-2-enoic acid methyl ester 
• 132375-75-8 ((2S,3S)-3-{(3S,4aR,6R,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-octahydro-pyrano[3,2-b]pyran-2-ylmethyl}-oxiranyl)-methanol 
• 132408-52-7 (2R,3S)-3-{(3S,4aR,6R,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-octahydro-pyrano[3,2-b]pyran-2-ylmethyl}-oxirane-2-carbaldehyde 
• 132375-77-0 (E)-3-((2S,3S)-3-{(3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-octahydro-pyrano[3,2-b]pyran-2-ylmethyl}-oxiranyl)-acrylic acid methyl ester 
• 132375-78-1 (E)-3-{(2R,3S,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-decahydro-1,8,10-trioxa-anthracen-2-yl}-acrylic acid methyl ester 

Downstream Products

• 132375-30-5 (2R,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,3-bis-ethylsulfanyl-decahydro-1,8,10-trioxa-anthracene-2-carbaldehyde 
• 205864-92-2 C₄₇H₇₄O₇S₂Si₂ 
• 221381-17-5 C₄₇H₇₆O₇S₂Si₂ 
• 221381-16-4 C₄₉H₈₀O₈Si₃ 
• 221381-15-3 C₄₉H₈₂O₈Si₃ 
• 205865-14-1 (2R,4S,5R)-4-((Z)-3-{(2R,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,3-bis-ethylsulfanyl-decahydro-1,8,10-trioxa-anthracen-2-yl}-allyl)-2-phenyl-[1,3]dioxan-5-ol 
• 221381-14-2 C₅₁H₈₄O₉Si₃ 
• 221381-13-1 5-benzyloxy-2-{3-[5-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-propenyl}-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,3-bis-ethylsulfanyl-decahydro-1,8,10-trioxa-anthracene 
• 132375-86-1 (Z)-(4aR,6S,7R,10aS)-6-{(Z)-3-[(2R,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-3,3-bis-ethylsulfanyl-7-(3-hydroxy-propyl)-decahydro-1,8,10-trioxa-anthracen-2-yl]-allyl}-2-phenyl-4,4a,6,7,10,10a-hexahydro-1,3,5-trioxa-benzocycloocten-7-ol 
• 132375-90-7 C₄₉H₆₄O₉Si 
• 132375-91-8 C₅₄H₇₂O₁₀Si 
• 132375-89-4 C₅₆H₆₈O₉Si 
• 132375-92-9 C₅₄H₇₂O₁₁Si 
• 132375-88-3 C₅₇H₇₀O₉SSi 

Relevant academic research and scientific papers

Total synthesis of brevetoxin A: Part 3: Construction of GHIJ and BCDE ring systems

Successful syntheses of highly complex intermediates 2 (GHIJ ring system) and 3 (BCDE ring system) for the total synthesis of brevetoxin A (1) are described. Several of our methodologies were utilized to achieve this goal: i) hydroxy epoxide cyclizations