Phenylselenium trichloride, preparation and use as a vinylic chlorination reagent

Article abstract of DOI:10.1080/00397919608003737

Phenylselenium trichloride (1) is prepared from benzeneseleninic acid (2) and thionyl chloride and used to effect vinylic chlorination, viz. the conversion of 3-chloro-2-chloromethyl-1-propene (4) into 2-chloromethyl-1,3-dichloropropene (3).

Full text of DOI:10.1080/00397919608003737

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Phenylselenium Trichloride,
Preparation and Use as a
Vinylic Chlorination Reagent
a
a
Nicolai Stuhr-Hansen , Lars Henriksen & Janos T.
a b
Kodra
a
Department of Chemistry , University of
Copenhagen, The H. C. Ørsted Institute ,
Universitetsparken 5, DK-2100, Copenhagen Ø,
Denmark
b
Laboratory for Organic Chemistry, E.T.H. , Zurich,
CH-8092, Switzerland
Published online: 21 Aug 2006.
To cite this article: Nicolai Stuhr-Hansen , Lars Henriksen & Janos T. Kodra (1996)
Phenylselenium Trichloride, Preparation and Use as a Vinylic Chlorination Reagent,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 26:18, 3345-3350, DOI: 10.1080/00397919608003737
To link to this article: http://dx.doi.org/10.1080/00397919608003737
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