132610-94-7

Upstream product

• 67-56-1 methanol 
• 132610-89-0 (-)-(R)-2-methyl-5-isopropenyl-3-phenylcyclohex-2-en-1-one 
• 145490-09-1 2-phenylcarveol 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 132611-04-2 (1S,4S)-1,8-Dimethyl-8-methoxy-6-phenylbicyclo<2.2.2>oct-5-en-2-one 
• 132696-81-2 (-)-(1S,4S,8R)-1,8-Dimethyl-8-methoxy-6-phenylbicyclo<2.2.2>oct-5-en-2-one 
• 132610-76-5 4-Bromo-1,5-dimethyl-7-phenyl-bicyclo[3.2.1]oct-6-en-2-one 
• 132610-75-4 (S)-8-Bromo-1,8-dimethyl-6-phenyl-bicyclo[2.2.2]oct-5-en-2-one 

Relevant academic research and scientific papers

Radical cyclisation strategies to bridged systems. Regioselective construction of chiral bicyclo [2.2.2] and [3.2.1] octanes via 6-exo trig and 5-exo trig radical cyclisation reactions

Radical cyclisation reaction of the bromoenones 6 and 7, obtained from (R)-phenyl carvone 3, gave a mixture of bicyclo [2.2.2] and [3.2.1] octanones via competitive 6-exo trig and 5-exo trig modes. On the other hand, radical cyclisation reaction of the al

Cyclopropanes via an Efficient 3-Exo Trig Radical Cyclisation Reaction

The first examples of an exclusive formation of a cyclopropane via the 3-exo trig radical cyclisation of homoallyl bromides 13 and 14 are reported.