132815-95-3Relevant academic research and scientific papers
Palladium-catalyzed phenyl-selenylation with n-Bu3SnSePh in one-pot two-step reactions
Bonaterra, Mariana,Martín, Sandra E.,Rossi, Roberto A.
, p. 3511 - 3515 (2006)
We have studied the Pd-catalyzed cross-coupling reaction of a stannane derived from selenium n-Bu3SnSePh (1) with aryl and perfluoroalkyl iodides. Herein a very efficient one-pot two-step selenylation reaction to form a C-Se bond is reported. Ph2Se2 reacts with Na metal in liquid ammonia yielding PhSe- ions. To this solution n-Bu3SnCl was added to afford 1, which was introduced in the palladium-catalyzed coupling reaction without isolation. These reactions afford functionalized diarylselenides and phenylperfluroalkyl selenides from good to high yields (38-98%).
Perfluoroalkylphosphines and arsines obtained by Pd-catalyzed cross-coupling reaction with organoheteroatom stannanes
Lanteri, Mario N.,Rossi, Roberto A.,Martín, Sandra E.
experimental part, p. 3425 - 3430 (2010/01/18)
Pd-catalyzed cross-coupling reaction of organoheteroatom stannanes containing elements of the groups 15 (P, As) and 16 (Se) with perfluoroalkyl iodides (RfI) was studied. Herein, a one-pot two-step reaction to form P-Rf, As-Rf/
A convenient access to perfluoroalkyl selenoethers selenyl chlorides
Magnier,Vit,Wakselman
, p. 1260 - 1262 (2007/10/03)
The treatment of diselenides with different perfluoroalkyl iodides in the presence of sodium hydroxymethanesulfinate led to perfluoroalkyl selenides in fair to good yields. The reaction between benzyl perfluorooctyl selenide chlorine, or sulfuryl chloride
PERFLUOROALKYL-SELENATION OF OLEFINS
Uneyama, Kenji,Kitagawa, Kouichi
, p. 375 - 378 (2007/10/02)
Perfluoroalkyl-selenation of olefins has been performed by the reaction of diphenyl diselenide with sodium borohydride followed with perfluoroalkyl halides (RfX) and olefins where one electron transfer from phenylseleno anion to RfX occurs, generating per
