132816-14-9Relevant academic research and scientific papers
Asymmetric Induction in Reductively Initiated -Wittig and Retro -Brook Rearrangements of Secondary Carbanions
Hoffmann, Rolf,Brueckner, Reinhard
, p. 1471 - 1484 (2007/10/02)
The synthesis of O,S-acetals and the lithium naphthalenide initiated rearrangement reactions thereof are described.O,S-Acetal 8a resulted from trapping of the 1,4-dipole 7 with thiophenol.O,S-Acetals 16a and b were obtained from aldehydes 14a/b by a one-p
A direct synthesis of O,S-acetals from aldehydes
Kusche, Andreas,Hoffmann, Rolf,Muenster, Ingo,Keiner, Petra,Brueckner, Reinhard
, p. 467 - 470 (2007/10/02)
In the presence of catalytic to stoichiometric amounts of trimethylsilyl triflate, 1:1:1 mixtures of silyl ethers, phenyl(trimethylsilyl)sulfide, and aldehydes give O,S-acetals in fair to good yields.
