1329426-09-6Relevant articles and documents
The liquid crystal Click procedure for oligothiophene-Tethered phthalocyanines-self-Assembly, alignment and photocurrent
Dechant, Moritz,Fujii, Akihiko,Lehmann, Matthias,Ozaki, Masanori,Uzurano, Genya
, p. 5689 - 5698 (2021)
A series of star-shaped liquid crystals (LCs) with a phthalocyanine donor core, oligothiophene antennae and fullerene acceptors have been successfully prepared. This hierarchical self-Assembly results in a nanosegregated helical donor-Acceptor-Antennae LC-system promoted by the recently discovered Click procedure. This model system reveals all photophysical prerequisites for energy conversion, charge generation and transport. Uniform amorphous thin films of 150 nm could be produced by bar-coating. Annealing did not only induce the formation of columns via the Click procedure but also partially homeotropically aligned the non-clearing sample in a sandwich geometry (ITO and Ag/MoO3). This has been confirmed by microscopic studies and the measurement of photocurrent, which increased by a factor of 300 after the annealing step.
The solution, an organic semiconductor material, the organic semiconductor film, electronic devices and electronic equipment
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Paragraph 0186; 0187, (2018/01/17)
A solution includes an organic solvent and a compound dissolved in the organic solvent, having the following formula (1): wherein R1 represents an aromatic group which may have a substituent or an alkyl group which may have a substituent; R2 and R3 independently represent an alkyl group which may have a substituent, an alkoxy group which may have a substituent, an alkylthio group which may have a substituent or a hydrogen atom, and may form a ring together; X represents an alkyl group having 4 to 6 carbon atoms, which may have a substituent; and n represents 1, 2 or 3.