1333822-90-4Relevant academic research and scientific papers
Mechanochemical Rhodium(III)-Catalyzed C-H Bond Amidation of Arenes with Dioxazolones under Solventless Conditions in a Ball Mill
Hermann, Gary N.,Bolm, Carsten
, p. 4592 - 4596 (2017/07/24)
A procedure for the direct mechanochemical rhodium(III)-catalyzed C-H bond amidation of arenes with 1,4,2-dioxazol-5-ones as the nitrogen source has been developed. The transformation proceeds under solventless conditions and does not require additional h
TRIFLUOROMETHYL GROUP-CONTAINING OXAZINE AND METHOD OF PRODUCING THE SAME
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, (2017/03/17)
PROBLEM TO BE SOLVED: To provide a trifluoromethyl group-containing oxazine useful as a synthetic intermediate in medical and agricultural chemical and electronic material fields, and to provide a production method suitable for industrial production. SOLU
Enantioselective halocyclization using reagents tailored for chiral anion phase-transfer catalysis
Wang, Yi-Ming,Wu, Jeffrey,Hoong, Christina,Rauniyar, Vivek,Toste, F. Dean
, p. 12928 - 12931 (2012/10/08)
A chiral anion phase-transfer system for enantioselective halogenation is described. Highly insoluble, ionic reagents were developed as electrophilic bromine and iodine sources, and application of this system to o-anilidostyrenes afforded halogenated 4H-3,1-benzoxazines with excellent yield and enantioselectivity.
Radical intermediates in the photorearrangement of 3-hydroxyindolic nitrones
Alberti, Angelo,Astolfi, Paola,Carloni, Patricia,Doepp, Dietrich,Greci, Lucedio,Rizzoli, Corrado,Stipa, Pierluigi
, p. 6889 - 6894 (2011/10/05)
A number of 3-hydroxy substituted indolic nitrones were found to quantitatively photorearrange to (2-benzoylamino)phenyl ketones upon UV-A irradiation. EPR-Spin Trapping experiments suggest that the process, which is believed to proceed via the formation
