133511-55-4Relevant academic research and scientific papers
An efficient one-pot protocol for the synthesis of phenyl substituted 3-silatetrahydropyrans
Kirpichenko, Svetlana V.,Shainyan, Bagrat A.
, p. 599 - 604 (2015)
A new facile and efficient one-pot procedure for the synthesis of 3-phenyl-3-silatetrahydropyrans with an easily functionalized Si-Ph bond was developed. The method is based on the intramolecular cyclization of chloromethyl(3-hydroxypropyl)phenylsilanes using the n-Bu4NBr/i-Pr2NEt combination. As an example of functionalization, the synthesis of the first 3-silatetrahydropyran with an exocyclic RO-Si bond is reported.
Synthesis and conformational analysis of 1,3-azasilinanes
Shainyan, Bagrat A.,Kirpichenko, Svetlana V.,Kleinpeter, Erich
experimental part, p. 7494 - 7501 (2012/09/21)
1-Isopropyl-3-methyl-3-phenyl-1,3-azasilinane 1 and 1-isopropyl-3,3- dimethyl-1,3-azasilinane 2 were synthesized and a detailed analysis of their NMR spectra, conformational equilibria and ring inversion processes is presented. Low temperature 1/sup
Rearrangements of α-Halosilanes Induced by Intramolecular Nucleophilic Attack at Silicon
Hudrlik, Paul F.,Abdallah, Yousef M.,Hudrlik, Anne M.
, p. 6743 - 6746 (2007/10/02)
Migrations of organic groups from silicon to carbon are facilitated by intramolecular attack by alkoxide at silicon.
