61676-43-5Relevant academic research and scientific papers
Rearrangements of α-Halosilanes Induced by Intramolecular Nucleophilic Attack at Silicon
Hudrlik, Paul F.,Abdallah, Yousef M.,Hudrlik, Anne M.
, p. 6743 - 6746 (2007/10/02)
Migrations of organic groups from silicon to carbon are facilitated by intramolecular attack by alkoxide at silicon.
BASE CLEAVAGE OF THE BENZYL-SILICON BOND IN PhCH2SiMe2(CH2)nOH (n = 2 or 3) COMPOUNDS
Eaborn, Colin,Mahmoud, Foad M.S.
, p. 13 - 16 (2007/10/02)
The compounds PhCH2SiMe2(CH2)nOH with n = 2 or 3 are cleaved 0.75 and 95-135 times, respectively, as readily as PhCH2SiMe3 by NaOMe/MeOH at 50 deg C.The high reactivity of the compound with n = 3 may arise from intramolecular attack of the alkoxide centre
