133552-01-9

Basic information

• Product Name: Silane, (1,1-dimethylethyl)[[(1S)-1-ethenylhexyl]oxy]diphenyl-
• CAS NO: 133552-01-9
• Molecular Formula: C24H34OSi
• Molecular Weight: 366.619
• Mol File: 133552-01-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)[[(1S)-1-ethenylhexyl]oxy]diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)[[(1S)-1-ethenylhexyl]oxy]diphenyl-(133552-01-9)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)[[(1S)-1-ethenylhexyl]oxy]diphenyl-(133552-01-9)

Safety Data

• Hazardous Substances Data: 133552-01-9(Hazardous Substances Data)

Upstream product

• 3391-86-4 (R)-1-octene-3-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 3391-86-4 1-octen-3-ol 
• 110-53-2 1-Bromopentane 
• 383136-06-9 1-(2,2-dimethyl-1,3-dioxolan-4-yl)-3-hexyn-1-ol 
• 93414-86-9 (2R,3S)-1,2-O-(isopropylidene)-octane-1,2,3-triol 

Downstream Products

• 93292-63-8 (S)-2-(tert-butyldiphenylsilyloxy)heptanal 
• 1585968-97-3 [(5S,6R)-5-(methoxymethoxy)undec-1-en-6-yloxy](tert-butyl)diphenylsilane 
• 1585968-98-4 [(5R,6R)-5-(methoxymethoxy)undec-1-en-6-yloxy](tert-butyl)diphenylsilane 
• 94292-89-4 4-{(4S,5R)-5-[(1E,3E,5E,7E)-(S)-9-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-1,3,5,7-tetraenyl]-2-oxo-[1,3]dioxolan-4-yl}-butyric acid ethyl ester 
• 94235-56-0 (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester 

Relevant articles and documents

Chemoenzymatic Asymmetric Total Synthesis of Nonanolide (Z)-Cytospolides D, e and Their Stereoisomers

Chemoenzymatic asymmetric total synthesis of the (Z)-isomer of the naturally occurring decanolide cytospolides D, E and six stereoisomers is reported. The main highlight of the synthetic venture involves ring-closing metathesis (RCM) reaction of a suitably functionalized ester compound, which was assembled by the Yamaguchi coupling of the required acid and alcohol fragments. The alcohol fragment was accessed by two alternative chemoenzymatic processes, one being hydroxynitrile lyase mediated hydrocyanation, whereas lipase-catalyzed transesterification was the key sep in the second route. The acid fragment was constructed by an enantioselective enzymatic desymmetrization (EED) of prochiral 2-methyl-1,3-propanediol and Corey-Bakshi-Shibata (CBS) mediated stereoselective carbonyl reduction.