94235-56-0

Basic information

• Product Name: (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester
• CAS NO: 94235-56-0
• Molecular Weight: 644.924
• Mol File: 94235-56-0.mol

Chemical Properties

• CAS DataBase Reference: (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester(94235-56-0)
• EPA Substance Registry System: (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester(94235-56-0)

Safety Data

• Hazardous Substances Data: 94235-56-0(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 146444-84-0 Ethyl (5S,6R)-5-ethoxycarbonyloxy-6,7-O-isopropylidene-6,7-dihydroxyhept-2-ynoate 
• 133988-96-2 (5S,6R)-5-Ethoxycarbonyloxy-6,7-O-isopropylidene-5,6,7-trihydroxyheptanoate 
• 146444-90-8 (5S,6R)-5-Ethoxycarbonyloxy-6,7-dihydroxy-heptanoic acid ethyl ester 
• 94235-52-6 ethyl 4-((4S,5R)-5-(hydroxymethyl)-2-oxo-1,3-dioxolan-4-yl)butanoate 
• 133988-95-1 (S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-pent-2-ynoic acid ethyl ester 
• 93292-62-7 (2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-octane-1,2-diol 
• 93292-61-6 tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane 
• 72036-30-7 ethyl 3-lithiopropiolate 
• 118908-15-9 (E)-(S)-4-(tert-Butyl-diphenyl-silanyloxy)-non-2-enal 
• 133988-97-3 ethyl (4S)-(2E)-4-tert-butyldiphenylsilyloxy-2-nonenoate 
• 93292-64-9 (4S),(2E)-4-O-tert-butyldiphenylsilyloxy-2-nonenol 
• 93292-65-0 1-bromo-(4S),(2E)-4-tert-butyldiphenylsilyloxy-2-nonene 
• 93292-63-8 (S)-2-(tert-butyldiphenylsilyloxy)heptanal 

Relevant articles and documents

Synthesis of (2E,4E)-dienals by double formyl-olefination with an arsonium salt and its application in the syntheses of lipoxygenase metabolites of arachidonic acid

A new facile route to (2E,4E)-dienals by a double formyl-olefination with arsonium salts has been developed. By this method and with other arsonium reagents in the key step some lipoxygenase metabolites of arachidonic acid, lipoxin A4 and B4 and leukotriene B4, have been synthesized.

Lipoxins A4 and B4. Total Synthesis Including Deprotection Studies

The total synthesis of lipoxins A4 and B4 (LXA4 and LXB4) as well as of their all-trans isomers is reported.A study concerning the final steps of deprotection of silyl ether, cyclic carbonate and ethyl ester assisted by a high-speed scanning UV spectropho

TOTAL SYNTHESIS OF LIPOXINS A4 AND B4 FROM D-ISOASCORBIC ACID

A total convergent synthesis of lipoxins A4 and B4 has been carried out via four optically pure α-hydroxy and α,β-dihydroxyaldehydes, obtained from D-isoascorbic acid as a single starting material.Connection by a six carbons unit uses Wittig-type reaction