13362-63-5

Basic information

• Product Name: Quinoline, 4-[(1E)-2-phenylethenyl]-
• Synonyms: .4-trans-Styryl-chinolin;.4-trans-styryl-quinoline;.4-styryl-quinoline;4-styrylquinoline;.4-Styryl-chinolin;.4-Styrylchinolin
• CAS NO: 13362-63-5
• Molecular Formula: C17H13N
• Molecular Weight: 231.297
• Mol File: 13362-63-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Quinoline, 4-[(1E)-2-phenylethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 4-[(1E)-2-phenylethenyl]-(13362-63-5)
• EPA Substance Registry System: Quinoline, 4-[(1E)-2-phenylethenyl]-(13362-63-5)

Safety Data

• Hazardous Substances Data: 13362-63-5(Hazardous Substances Data)

Upstream product

• 491-35-0 C₆H₄NCH₂CHCCH₂ 
• 100-52-7 benzaldehyde 
• 5435-44-9 (E)-3-Ureido-but-2-enoic acid ethyl ester 
• 758640-21-0 N-Benzylaniline 
• 100-42-5 styrene 
• 3964-04-3 4-bromoquinoline 
• 100-51-6 benzyl alcohol 
• 100-46-9 benzylamine 

Downstream Products

• 5414-80-2 4-(2-phenylethyl)quinoline 
• 116030-17-2 1-[2]quinolyl-3-[4]quinolyl-2-phenyl-propane 
• 81340-60-5 1,3-di-[4]quinolyl-2-phenyl-propane 
• 486-74-8 4-quinolinic acid 
• 115984-31-1 (1α,2α,3β,4β)-1,3-Bis(4-chinolinyl)-2,4-diphenylcyclobutan 
• 4594-84-7 cis-4-Styrylquinoline 

Relevant articles and documents

Deaminative Olefination of Methyl N-Heteroarenes by an Amine Oxidase Inspired Catalyst

We explored the bioinspired o-quinone cofactor catalyzed aerobic primary amine dehydrogenation for a cascade olefination reaction with nine different methyl N-heteroarenes, including pyrimidines, pyrazines, pyridines, quinolines, quinoxolines, benzimidazoles, benzoxazoles, benzthiazoles, and triazines. An o-quinone catalyst phd (1,10-phenanthroline-5,6-dione) combined with a Br?nsted acid catalyzed the reaction. N-Heteroaryl stilbenoids were synthesized in high yields and (E)-selectivities under mild conditions using oxygen (1 atm) as the sole oxidant without needing transition-metal salt, ligand, stoichiometric base, or oxidant.

Iron/TEMPO-catalyzed direct aerobic oxidative coupling of methyl-mubstituted N-heteroazaarenes with alcohols

A novel direct oxidative coupling of methyl-substituted N-heteroazaarenes with alcohols has been developed to construct olefins under mild condition. The reaction is catalyzed by Fe(NO3)3·9H2O/TEMPO with oxygen as terminal oxidant. A variety of E-disubstituted olefins bearing diverse functional groups could be obtained selectively in moderate to excellent yields. The reaction is environmentally friendly and ligand-free.

Preparation method of trans-disubstituted olefin

The invention relates to the technical field of organic chemical synthesis, and in particular, relates to a preparation method of trans-disubstituted olefin. According to the preparation method, primary alcohol and methyl azacycle are taken as raw materials, transition metal salt, nitric oxide and alkali are taken as catalysts, an organic solution is taken as a reaction medium, and reaction is carried out in an oxygen atmosphere. According to the preparation method, a reaction by-product is only water, the environment is not polluted, the required transition metal catalyst is cheap and easy toobtain, the reaction does not need high temperature, and the reaction cost and the requirements on reaction conditions can be reduced.