1337990-07-4

Basic information

• Product Name: (2R,3S,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde
• Synonyms: (2R,3S,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde
• CAS NO: 1337990-07-4
• Molecular Weight: 539.628
• Mol File: 1337990-07-4.mol

Chemical Properties

• CAS DataBase Reference: (2R,3S,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde(1337990-07-4)
• EPA Substance Registry System: (2R,3S,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde(1337990-07-4)

Safety Data

• Hazardous Substances Data: 1337990-07-4(Hazardous Substances Data)

Upstream product

• 102093-90-3 ((1R,2S,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-pent-4-enyloxy)-tert-butyl-dimethyl-silane 
• 102208-53-7 (3R,4R,5R)-5-hydroxy-3,4,6-tribenzyloxy-1-hexene 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 67350-50-9 5-(hydroxymethyl)-1H-pyrrole-2-carboxaldehyde 
• 39604-60-9 pyrrole-2,5-biscarboxaldehyde 
• 1337989-88-4 5-((tetrahydro-2H-pyran-2-yloxy)methyl)-1-((3S,4S,5R)-3,4,6-tris(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-oxohexyl)-1H-pyrrole-2-carbaldehyde 
• 1337989-87-3 5-((tetrahydro-2H-pyran-2-yloxy)methyl)-1-((3R,4S,5R)-3,4,6-tris(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-hydroxyhexyl)-1H-pyrrole-2-carbaldehyde 
• 1337989-86-2 tert-butyldimethyl((2R,3S,4R)-1,3,4-tris(benzyloxy)-4-(oxiran-2-yl)butan-2-yloxy)silane 
• 1337989-73-7 5-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)-1H-pyrrole-2-carbaldehyde 
• 6249-04-3 (1H-pyrrole-2,5-diyl)dimethanol 

Relevant articles and documents

Total synthesis and stereochemical revision of acortatarins A and B

A first total synthesis of acortatarins A, B, and an enantiomer of the proposed structure of acortatarin B is described by using readily available d-sugars. This convergent total synthesis revealed the revision of the absolute configuration of acortatarin A and structural revision of acortatarin B. The key steps involved are regioselective epoxide opening with deprotonated 2,5-disubstituted pyrrole and spiroketalization.