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133844-84-5

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133844-84-5 Usage

Synthesis Reference(s)

Synthesis, p. 589, 1996 DOI: 10.1055/s-1996-4265

Check Digit Verification of cas no

The CAS Registry Mumber 133844-84-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,3,8,4 and 4 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 133844-84:
(8*1)+(7*3)+(6*3)+(5*8)+(4*4)+(3*4)+(2*8)+(1*4)=135
135 % 10 = 5
So 133844-84-5 is a valid CAS Registry Number.

133844-84-5Relevant articles and documents

Heteroaryl functionalised diacetylenes: Preparation and solid-state reactivity

Sarkar, Abhijit,Talwar, Satya S.

, p. 4141 - 4146 (1998)

Diacetylenes are known to undergo solid-state topochemical polymerisation to give polydiacetylenes. The reactivity of the monomer is controlled by the arrangement of the molecules in the crystal lattice wherein certain parametric conditions must be met for 1,4-addition to proceed. In the present paper, we investigated the structure-reactivity relationship of a class of diacetylene monomers. Heteroaryl moieties such as thiophene, benzo[b]thiophene and quinoline as one or both directly bound side groups of a diacetylene backbone were used. Thus various symmetrical as well as unsymmetrical diacetylenes were prepared and characterised. The solid-state polymerisation behaviour of these diacetylenes was studied in the light of their single-crystal X-ray structure. It was found that in order to react in the solid state, the diacetylenes must have the required lattice parameters. However, even when the required lattice parameters are met, the diacetylene monomers do not necessarily undergo solid-state 1,4-addition polymerisation, implying the existence of further controlling factors to determine reactivity.

One-Pot Palladium-Catalysed Synthesis of Diarylalkynes

Carpita, Adriano,Lessi, Alessandro,Rossi, Renzo

, p. 571 - 572 (1984)

-

Nanosized Pd(0)-arabinogalactan composites as catalysts in the Sonogashira reaction

Parshina,Tantsyrev,Grishchenko,Trofimov

, p. 412 - 416 (2013)

Zero-valent palladium nanoparticles stabilized by arabinogalactan polysaccharide matrix were successfully used for the first time as phosphine-free catalyst in the cross-coupling of terminal alkynes with aryl and hetaryl halides.

Rhodium-catalyzed oxidative coupling of benzoic acids with propargyl alcohols: An efficient access to isocoumarins

Luo, Feihua,He, Shuhua,Gou, Quan,Chen, Jinyang,Zhang, mingzhong

, (2021)

An efficient protocol of Rh(III)-catalyzed oxidative cyclization of benzoic acids with propargyl alcohols to give substituted isocoumarins under mild conditions was reported. A variety of substrates were applied in this reaction in yields up to 89%.

Cleavage of C–C and C–O Bonds to Form C–C Bonds: Direct Cross-Coupling between Acetylenic Alcohols and Benzylic Carbonates

Mi, Zhiyuan,Tang, Jiahao,Guan, Zhipeng,Shi, Wei,Chen, Hao

supporting information, p. 4479 - 4482 (2018/09/10)

A palladium-catalyzed cross-coupling reaction between C(sp) and C(sp3) centers was achieved in excellent yields via C–C bond cleavage and C–O bond cleavage. This procedure uses relatively stable acetylenic alcohols as reactants instead of unsta

Highly Efficient Synthesis of Multi-Substituted Allenes from Propargyl Acetates and Organoaluminum Reagents Mediated by Palladium

Zhang, Zhen,Shao, Xuebei,Zhang, Gang,Li, Qinghan,Li, Xinying

, p. 3643 - 3653 (2017/08/16)

A simple and mild catalytic S N 2′ substitution reaction of propargyl acetates with organoaluminum reagents is reported. The S N 2′ substitution reaction of propargyl acetates with organoaluminum reagents mediated by Pd(PhP 3) 2 Cl 2 (1 mol%)/PPh 3 (2 mol%)/K 2 CO 3 in tetrahydrofuran at 60 °C for 3-4 hours afforded the corresponding multi-substituted allenes in good yields (up to 94%) with high selectivities (up to 99%). The process was simple and easily performed, which offers an efficient method to synthesize the multi-substituted allene derivatives.

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