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N,N'-Di(4-biphenylyl)-N,N'-diphenylbenzidine, also known as SDD, is an organic chemical compound that is commonly used as a charge transport material in electrophotography and organic light-emitting diodes. It has been identified as a potential occupational carcinogen and may cause skin and eye irritation upon contact. Additionally, exposure to SDD has been linked to adverse effects on the reproductive system and liver in animal studies. As a result, the use and handling of N,N'-Di(4-biphenylyl)-N,N'-diphenylbenzidine should be done with caution and appropriate safety measures in place to minimize the risk of adverse health effects.

134008-76-7

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134008-76-7 Usage

Uses

Used in Electrophotography:
N,N'-Di(4-biphenylyl)-N,N'-diphenylbenzidine is used as a charge transport material in electrophotography for its ability to efficiently transport charges, improving the performance and quality of printed images.
Used in Organic Light-Emitting Diodes (OLEDs):
In the field of organic light-emitting diodes, N,N'-Di(4-biphenylyl)-N,N'-diphenylbenzidine is used as a charge transport material to enhance the efficiency and stability of the devices, leading to better display and lighting applications.
Used in Research and Development:
N,N'-Di(4-biphenylyl)-N,N'-diphenylbenzidine is also used in research and development for the study of charge transport mechanisms and the development of new materials with improved properties for various electronic applications.

Check Digit Verification of cas no

The CAS Registry Mumber 134008-76-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,4,0,0 and 8 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 134008-76:
(8*1)+(7*3)+(6*4)+(5*0)+(4*0)+(3*8)+(2*7)+(1*6)=97
97 % 10 = 7
So 134008-76-7 is a valid CAS Registry Number.
InChI:1S/C48H36N2/c1-5-13-37(14-6-1)39-21-29-45(30-22-39)49(43-17-9-3-10-18-43)47-33-25-41(26-34-47)42-27-35-48(36-28-42)50(44-19-11-4-12-20-44)46-31-23-40(24-32-46)38-15-7-2-8-16-38/h1-36H

134008-76-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N'-bis-biphenyl-4-yl-N,N'-diphenyl-benzidine

1.2 Other means of identification

Product number -
Other names N,N'-Bis-biphenyl-4-yl-N,N'-diphenyl-benzidin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:134008-76-7 SDS

134008-76-7Downstream Products

134008-76-7Relevant academic research and scientific papers

ORGANIC ELECTROLUMINESCENT DEVICE

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Paragraph 0087-0090, (2020/01/24)

To provide an organic EL device having low driving voltage, high luminous efficiency, and particularly a long lifetime by combining various materials for an organic EL device having excellent hole and electron injection/transport performances, electron blocking ability, stability in a thin-film state, and durability as materials for an organic EL device having high luminous efficiency and high durability so as to allow the respective materials to effectively reveal their characteristics. In the organic EL device having at least an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and a cathode, in this order, the hole injection layer includes an arylamine compound of the following general formula (1) and a radialene derivative of the following general formula (2).

COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF

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Paragraph 0335-0337, (2020/05/30)

The present invention relates to a novel compound, an organic electric element using the same, and an electronic device thereof. According to the present invention, a luminous efficiency, a color purity and a lifespan of the element can be improved and a driving voltage can be lowered. The organic electric element comprises: an anode; a cathode; and an organic material layer formed between the anode and the cathode.

Compound, organic electric element using the same, and an electronic device thereof

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Page/Page column 242; 243; 277; 280, (2018/08/07)

A compound represented by Formula 1. An organic electric element includes a first electrode, a second electrode, and an organic material layer including the compound of Formula 1. The organic material layer include a light emitting layer, a hole transport layer including a compound represented by Formula 2, and an emission-auxiliary layer including the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, color purity, and life span can be improved.

Metal-Free Oxidative C-C Coupling of Arylamines Using a Quinone-Based Organic Oxidant

Maddala, Sudhakar,Mallick, Sudesh,Venkatakrishnan, Parthasarathy

, p. 8958 - 8972 (2017/09/11)

A variety of arylamines are shown to undergo oxidative C-C bond formation using quinone-based chloranil/H+ reagent as the recyclable organic (metal-free) oxidant system to afford benzidines/naphthidines. Arylamines (3°/2°) designed with various substituents were employed to understand the steric as well as electronic preferences of oxidative dimerization, and a mechanism involving amine radical cation has been proposed. The tetraphenylbenzidine derivative obtained via oxidative C-C coupling has been further converted to blue-emissive hole-transporting material via a simple chemical transformation. This study highlights the preparation of novel HTMs in a simple, economic, and efficient manner.

METHOD OF PRODUCING AROMATIC AMINO COMPOUNDS

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Page/Page column 6; 7, (2011/10/31)

[Problem] To provide a method of producing an aromatic amino compound by using a primary or secondary amine compound and a halogenated aromatic compound as starting materials, and relying upon the Ullmann reaction, the method being capable of obtaining the highly pure aromatic amino compound in high yields and inexpensively. [Means for Solution] A method of producing an aromatic amino compound by using a primary or secondary amine compound having an aromatic ring group and a halogenated aromatic compound as starting materials, reacting the amine compound with the halogenated aromatic compound in the presence of a copper catalyst and a base so as to produce the aromatic amino compound having a structure in which an aromatic ring group derived from the halogenated aromatic compound is coupled to the amino group of the amine compound, wherein the amine compound and the halogenated aromatic compound are reacted together under a condition where an aromatic oxycarboxylic acid having a hydroxyl group and a hydroxycarbonyl group that are bonded to neighboring carbon atoms, is made present together with the copper catalyst and the base.

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