Reactions of methylchlorodisilanes with Grignard reagents

DOI: 10.1007/BF00696930

Source and publish data:

Russian Chemical Bulletin p. 927 - 930 (1995)

Update date:2022-08-03

Topics:

Authors:

Semenov, V. V.

Ladilina, E. Yu.

Chesnokova, T. A.

Elistratova, N. K.

Kurskii, Yu. A.

Makarenko, N. P.

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Article abstract of DOI:10.1007/BF00696930

Reactions of Cl2MeSiSiMeCl2 with RMgCl make it possible to obtain and isolate pure disilanes containing a smaller number of functional groups, namely, RMeClSiSiMeCl2 (R = Ph), RMeClSiSiMeRCl (R = Prⁱ, Ph), and R2MeSiSiMeRCl (R = Buⁱ).The reaction of Cl2MeSiSiMeCl2 with BuⁿMgCl is the least selective.The chlorides obtained were reduced with LiAlH4 into the corresponding hydrides.

Full text of DOI:10.1007/BF00696930

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