13478-18-7Relevant articles and documents
Perrin, C.,Sergent, M.,Traon, F. Le,Traon, A. Le
, p. 197 - 204 (1978)
Formation of Molybdenum-bearing Ferrites, Fe(3-x)MoxO4 (x= 0.04-0.19), in Aqueous Suspension by Air Oxidation
Kanzaki, Tadao,Furukawa, Haruhiko,Katsura, Takashi
, p. 1197 - 1198 (1983)
Molybdenum-bearing ferrites (Mo:Fetot. mol ratios 0.015-0.069:1) have been formed by air oxidation of iron(II) hydroxide suspensions, which were prepared in the presence of Mo(III) ions, at Mo:Fetot. mol ratios of 0.032-0.0326:1 in t
Improved preparations of molybdenum coordination compounds from tetrachlorobis(diethyl ether)molybdenum(IV)
Stoffelbach, Fran?ois,Saurenz, Dirk,Poli, Rinaldo
, p. 2699 - 2703 (2007/10/03)
The reduction of MoCl5 with metallic tin in diethyl ether provides a rapid and convenient entry to [MoCl4(OEt2)2] This compound can be transformed easily and in high yields into a variety of other useful synthon
Ternary molybdenum(III) chlorides
Beier,Seifert
, p. 63 - 71 (2008/10/08)
The phase diagrams of ACl/MoCl3 (A = Na, K, Rb, Cs) were elucidated by DTA measurements in sealed quartz ampoules in the range of 0-40 mol% MoCl3. The samples were prepared from alkali metal chlorides and the compounds A3MoCl6 or A3Mo2Cl9. The 3:1 compounds with A = Na, Rb, Cs were obtained by sintering mixtures of 3ACl+MoCl3; the enneachlorides A3Mo2Cl9 with A = K, Rb, Cs were precipitated from solutions of MoCl3·3H2O and ACl in formic acid. Congruently melting compounds A3MoCl6 exist in all four systems, incongruently melting enneachlorides A3Mo2Cl9 in systems with A = K, Rb, Cs. Still unknown structures were determined by analog-indexing powder patterns according to known structure families. Especially Cs3MoCl6 is isotypic with the recently found Cs3CrCl6 structure. Additionally, the unit cell parameters were determined for the compounds A3MoCl5·H2O (A = K, Rb, Cs) analogous to Cs2TiCl5·H2O, whose structure was determined by single crystal measurements.
