13497-54-6

Basic information

• Product Name: 3,3'-Dichlorobiphenyl-4,4'-diol
• Synonyms: 3,3'-Dichlorobiphenyl-4,4'-diol
• CAS NO: 13497-54-6
• Molecular Formula: C12H8Cl2O2
• Molecular Weight: 0
• Mol File: 13497-54-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,3'-Dichlorobiphenyl-4,4'-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3'-Dichlorobiphenyl-4,4'-diol(13497-54-6)
• EPA Substance Registry System: 3,3'-Dichlorobiphenyl-4,4'-diol(13497-54-6)

Safety Data

• Hazardous Substances Data: 13497-54-6(Hazardous Substances Data)

Upstream product

• 92-88-6 4,4'-Dihydroxybiphenyl 
• 10026-13-8 phosphorus pentachloride 
• 53197-57-2 4,4'-dihydroxy-[1,1'-biphenyl]-2-carboxylic acid 
• 95-57-8 2-monochlorophenol 
• 7664-93-9 sulfuric acid 
• 91-94-1 3,3'-dichlorobenzidine 
• 64-19-7 acetic acid 

Relevant articles and documents

Ammonium Salt-Catalyzed Highly Practical Ortho-Selective Monohalogenation and Phenylselenation of Phenols: Scope and Applications

An ortho-selective ammonium chloride salt-catalyzed direct C-H monohalogenation of phenols and 1,1′-bi-2-naphthol (BINOL) with 1,3-dichloro-5,5-dimethylhydantoin (DCDMH) as the chlorinating agent has been developed. The catalyst loading was low (down to 0.01 mol %) and the reaction conditions were very mild. A wide range of substrates including BINOLs were compatible with this catalytic protocol. Chlorinated BINOLs are useful synthons for the synthesis of a wide range of unsymmetrical 3-aryl BINOLs that are not easily accessible. In addition, the same catalytic system can facilitate the ortho-selective selenylation of phenols.

Preparation, gas chromatographic behavior, and spectroscopic properties of hydroxylated chlorobiphenyls.

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