13497-57-9

Basic information

• Product Name: tris(p-(dimethylamino)phenyl)arsine
• Synonyms: tris(p-(dimethylamino)phenyl)arsine
• CAS NO: 13497-57-9
• Molecular Weight: 435.444
• Mol File: 13497-57-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tris(p-(dimethylamino)phenyl)arsine(CAS DataBase Reference)
• NIST Chemistry Reference: tris(p-(dimethylamino)phenyl)arsine(13497-57-9)
• EPA Substance Registry System: tris(p-(dimethylamino)phenyl)arsine(13497-57-9)

Safety Data

• Hazardous Substances Data: 13497-57-9(Hazardous Substances Data)

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 7784-34-1 arsenic trichloride 
• 7647-01-0 hydrogenchloride 
• 91484-30-9 (4-dimethylamino-phenyl)-arsonic acid 
• 13190-50-6 4-dimethylaminophenyllithium 
• 202211-52-7 tris(2,6-dimethoxybenzenethiolato)arsine 

Relevant articles and documents

Two-step synthesis of triarylmetals (As, Sb, Bi) starting from the metal oxides and 2,6-dimethoxybenzenethiol

Reported here is a new synthetic method of triarylmetals MAr3 (M = As, Sb, Bi). It is composed of two-step reactions starting from the metal oxides: (1) A reaction of the metal oxide with 2,6-dimethoxybenzenethiol ΦSH [Φ = 2,6-(MeO)2C6H3] in the presence of acid to give the thiolatometals M(SΦ)3, and (2) A reaction of M(SΦ)3 with organolithium reagent LiAr to give MAr3 (Ar = Ph, 4-MeC6H4, 4-Me2NC6H4, Φ). Since ΦSH is odorless and crystalline, most of it can be recovered after the reactions without difficulty for repeated usages. The intermediates M(SΦ)3 are also crystalline and inert against hydrolysis.