13504-46-6Relevant academic research and scientific papers
Cycloaddition reactions of sodium dinitroxytrioxide (Angeli's salt)
Torun, Lokman,Mohammad, Taj,Morrison, Harry
, p. 5279 - 5282 (1999)
Angeli's salt undergoes a quantitative reaction with 1,3- diphenylisobenzofuran in a methanol/water solution at room temperature to give a product (1) explicable by an initial [4+2] cycloaddition reaction. Under the same conditions, Angeli's salt reacts with 1-naphthaldehyde to give 1-naphthoic acid in good yield. This reaction can also be explained by an initial [2+2] cycloaddition to give a hydroxamic acid, which is then hydrolyzed to the carboxylic acid.
Controlled photochemical release of nitric oxide from O2-naphthylmethyl- and O2-naphthylallyl-substituted diazeniumdiolates
Bushan, K. Mani,Xu, Hua,Ruane, Patrick H.,D'Sa, Raechelle A.,Pavlos, Christopher M.,Smith, Joseph A.,Celius, Tevye C.,Toscano, John P.
, p. 12640 - 12641 (2007/10/03)
The photochemistry of O2-naphthylmethyl- and O2-naphthylallyl-substituted diazeniumdiolates has been investigated. Electron-donating methoxy group substitution is shown to have a significant effect on the observed photochemistry, with the appropriate substitution pattern resulting in efficient diazeniumdiolate photorelease. Observed nitric oxide release rates from these photoprecursors are consistent with those expected for normal thermal dissociation of the diazeniumdiolate in aqueous solutions and show the same pH dependence. Copyright
Facile conversion of acetals to nitriles
Yamauchi
, p. 2042 - 2043 (2007/10/02)
Aliphatic and aromatic acetals are easily and efficiently converted to the corresponding nitriles by reaction with hydroxylamine hydrochloride in refluxing absolute ethanol.
Direct carbohydroximoylation of aromatics with primary nitroalkanes in triflic acid (TFSA)
Coustard, Jean-Marie,Jacquesy, Jean-Claude,Violeau, Bruno
, p. 8085 - 8086 (2007/10/02)
Primary nitroalkanes react with aromatics in triflic acid to yield arylated oximes at 70-80°C.
