1351395-57-7

Basic information

• Product Name: (E)-1-bromo-2-(3,3,3-trifluoroprop-1-en-1-yl)benzene
• Synonyms: (E)-1-bromo-2-(3,3,3-trifluoroprop-1-en-1-yl)benzene
• CAS NO: 1351395-57-7
• Molecular Weight: 251.046
• Mol File: 1351395-57-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (E)-1-bromo-2-(3,3,3-trifluoroprop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-bromo-2-(3,3,3-trifluoroprop-1-en-1-yl)benzene(1351395-57-7)
• EPA Substance Registry System: (E)-1-bromo-2-(3,3,3-trifluoroprop-1-en-1-yl)benzene(1351395-57-7)

Safety Data

• Hazardous Substances Data: 1351395-57-7(Hazardous Substances Data)

Upstream product

• 887144-97-0 Togni's reagent 
• 2039-88-5 2-bromostyrene 
• 7345-79-1 2-bromocinnamic acid 
• 2926-29-6 Langlois reagent 
• 7345-79-1 2-bromocinnamic acid 
• 1465812-79-6 2-[(2,2,2-trifluoroethyl)sulfonyl]benzo[d]thiazole 
• 6630-33-7 ortho-bromobenzaldehyde 
• 645413-74-7 (E)-1-bromo-2-(2-iodovinyl)benzene 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 65185-68-4 (E)-2-bromo-β-nitrostyrene 

Relevant articles and documents

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent

An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electrophilic trifluoromethylating reagent has been developed. The reactions proceeded smoothly to give trifluoromethylated alkenes in good to excellent yields. The results provided a versatile approach for the construction of Cvinyl-CF3 bonds without using prefunctionalized substrates.

Electrochemical Decarboxylative Trifluoromethylation of α, β-Unsaturated Carboxylic Acids with CF3SO2Na

A new method for the synthesis of vinyl trifluoromethyl compounds from α, β-unsaturated carboxylic acids and CF3SO2Na has been developed. This electrochemical decarboxylative trifluoro-methylation was found to be highly stereoselective and afforded products in good yields with wide substrate scope under metal-free and external chemical oxidant-free conditions.

Silver(I)-catalyzed denitrative trifluoromethylation of β-nitrostyrenes with CF3SO2Na

A novel and convenient approach to the synthesis of substituted β-trifluoromethyl styrenes via a silver(I)-catalyzed denitrative trifluoromethylation with CF3SO2Na under relatively mild conditions has been developed. This protocol delivered excellent stereoselectivity and showed wide substrate tolerance.