1352034-36-6

Basic information

• Product Name: C₃₃H₄₁F₃O₆
• Synonyms: C₃₃H₄₁F₃O₆
• CAS NO: 1352034-36-6
• Molecular Weight: 590.68
• Mol File: 1352034-36-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₃H₄₁F₃O₆(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₃H₄₁F₃O₆(1352034-36-6)
• EPA Substance Registry System: C₃₃H₄₁F₃O₆(1352034-36-6)

Safety Data

• Hazardous Substances Data: 1352034-36-6(Hazardous Substances Data)

Upstream product

• 156723-09-0 3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone 
• 156723-11-4 11,12,14-trimethoxy-9(10->20)-5aH-abeo-abieta-5(10),8,11,13-tetraen-1-one 
• 156723-08-9 4,4-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenyl-methyl]-1,3-cyclohexanedione 
• 156723-10-3 3-ethenyl-4,4-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone 
• 156723-05-6 methyl 4-(1-methylethyl)-2,3,5-trimethoxybenzoate 
• 156723-07-8 2-(1-methylethyl)-1,3,4-trimethoxy-5-(bromomethyl)benzene 
• 156723-06-7 4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl alcohol 
• 36873-96-8 2,3,5-trimethoxybenzoic acid 
• 23030-39-9 1-bromo-2,3,5-trimethoxybenzene 
• 60241-78-3 3-(1-methylethyl)-1,2,4-trimethoxybenzene 
• 562-46-9 4,4-dimethylcyclohexane-1,3-dione 
• 1352034-31-1 (S)-11,12,14-trimethoxy-9(10->20)-5aH-abeo-abieta-1(10),8,11,13-tetraen-1-ol 
• 39637-99-5 (S)-(+)-2-methoxy-2-trifluoromethyl-2-phenylacetyl chloride 
• 866464-91-7 4-(1-methylethyl)-2,3,5-trimethoxybenzaldehyde 

Relevant articles and documents

Synthesis of (±)- and (+)-perovskone

A biomimetic synthesis of the triterpene (±)-perovskone was achieved featuring a remarkable polycyclization process in which three rings, four bonds, and five stereocenters were created in a single operation in 82% yield. This convergent synthesis required 16 steps, starting from vanillin, and proceeded in 9% overall yield. A second route to prepare optically active quinone 2 took 15 steps in 36% overall yield and featured a palladium-catalyzed reductive allylic transposition to establish the C-5 chirality stereospecifically. Quinone (-)-2 was converted to (+)-perovskone (1) via a polycyclization cascade, which created four rings, five bonds, and six stereocenters in a single operation in 50% yield.