36873-96-8Relevant articles and documents
Synthesis of polyhydroxylated flavonoids bearing a lipophilic decyl tail as potential therapeutic antioxidants
Caldwell, Stuart T.,McPhail, Donald B.,Duthie, Garry G.,Hartley, Richard C.
scheme or table, p. 23 - 33 (2012/03/07)
Antioxidants have potential for the treatment of stroke and neurodegeneration, and chimeric compounds that combine a flavon-3-ol head group related to myricetin and a lipophilic decyl tail are known to protect membranes from oxidative damage at least as well as vitamin E. New flavon-3-ols that are highly hydroxylated in the B ring in ways not found in natural flavon-3-ols and bearing a lipophilic decyl tail have been prepared from trimethoxy-and tetramethoxybenzoic acids accessed by lithiation-carboxylation reactions. Direct enolate acylation was preferred over Baker-Venkataraman rearrangement when there were methoxy groups at both the 2-and the 6-position of the benzoic acid derivatives.
Ga(IIl)-catalyzed cycloisomerization approach to (±)-icetexone and (±)-epi-icetexone
De Jesus Cortez, Felipe,Sarpong, Richmond
supporting information; experimental part, p. 1428 - 1431 (2010/07/03)
"Chemical eqation presented" A Ga(III)-catalyzed cycloisomerization reaction provides expedient access to a benzannulated cycloheptadiene bearing a cyano group, which has been applied to the syntheses of several icetexane diterpenoids including icetexone
A concise and efficient synthesis of protected actinoidic acid, the degradation product of vancomycin
Zhu, Jieping,Beugelmans, Rene,Bigot, Antony,Singh, Girij Pal,Bois-Choussy, Michele
, p. 7401 - 7404 (2007/10/02)
Protected actinoidic acid 2, one of the degradation products of vancomycin, has been efficiently synthesized by a convergent route which is amenable to large scale application as well as to asymmetric synthesis.