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NEW APPLICATIONS OF IMINOPHOSPHORANES. THE PREPARATION OF β-KETO CARBODIIMIDES AND THEIR REARRANGEMENT TO 2-AMINO-1,3-OXAZOLES
Froeyen, Paul
, p. 81 - 84 (2007/10/02)
β-Keto carbodiimides (3) have been synthesized by reacting 2-azido ketones (1) with triphenylphosphine in the presence of isocyanates/isothiocyanates; the former compounds (3) are readily transformed into 2-amino-1,3-oxazoles (4).Key words: Synthesis; imi
