1355696-29-5Relevant articles and documents
Gold(I)-catalyzed polycyclizations of polyenyne-type anilines based on hydroamination and consecutive hydroarylation cascade
Hirano, Kimio,Inaba, Yusuke,Takasu, Kiyosei,Oishi, Shinya,Takemoto, Yoshiji,Fujii, Nobutaka,Ohno, Hiroaki
, p. 9068 - 9080 (2011/12/16)
A hydroamination-double hydroarylation cascade using aniline derivatives bearing a trienyne moiety as the substrate was efficiently promoted by a gold(I) catalyst to produce benzo[a]naphtho[2,1-c]carbazole derivatives in good yields. This reaction is applicable to various substituted trienyne-type anilines, including 2,3-diethynylthiophene derivatives. The reaction of anilines bearing a tetraenyne and pentaenyne moiety allows direct construction of highly fused carbazoles by tetra- and pentacyclization, respectively, through hydroamination and consecutive hydroarylation without producing any theoretical waste products from the substrates.
