135774-34-4Relevant articles and documents
Facile synthesis of 2-fluoroindenones via a Knoevenagel condensation/palladium-catalyzed annulation
Su, Yue,Fang, Xiang,Zhou, Jun,Bian, Yizhen,Yang, Xueyan,Wu, Fanhong
, p. 76 - 80 (2018)
An efficient synthesis of 2-fluoroindenones was developed starting from simple o-bromo-2-fluroethenones and aldehydes. This domino reaction involved Knoevenagel condensation and intramolecular Heck coupling cyclization. A variety of 2-fluoroindenones were generated in good to excellent yields.
Synthesis of α-Fluoroketones from Vinyl Azides and Mechanism Interrogation
Wu, Shu-Wei,Liu, Feng
, p. 3642 - 3645 (2016/08/16)
An efficient and mild fluorination of vinyl azides for the synthesis of α-fluoroketones is described. The mechanistic studies indicated that a single-electron transfer (SET) and a subsequent fluorine atom transfer process could be involved in the reaction.
Metal-free, efficient oxyfluorination of olefins for the synthesis of α-fluoroketones
Yang, Qiang,Mao, Liu-Liang,Yang, Bin,Yang, Shang-Dong
supporting information, p. 3460 - 3463 (2014/07/21)
A novel oxyfluorination of olefin reactions has been developed. The reactions involve a metal-free and green catalytic system for the synthesis of α-fluoroketones which is an important building block for organic synthesis. Moreover, this reaction system exhibits great functional group tolerance.
