136025-65-5Relevant academic research and scientific papers
Diastereoselective Synthesis of Enantiomeric Tertiary Alcohols via Nucleophilic Additions to Protected D- and L-Erythrulose Derivatives
Carda, Miguel,Gonzales, Florenzi,Rodriguez, Santiago,Marco, J. Alberto
, p. 1511 - 1514 (2007/10/02)
The diastereoselectivity of the addition of several organometallic reagents to the carbonyl group of protected D- and L-erythrulose derivatives has been investigated.Tertiary alcohols are stereoselectively formed, the diastereomeric ratio being markedly d
A Synthesis of Natural α-Tocopherol Intermediate
Sugai, Takeshi,Watanabe, Naoyuki,Ohta, Hiromichi
, p. 371 - 376 (2007/10/02)
(S)-(-)-6-Hydroxy-2,5,7,8-tetramethyl-2-chromanmethanol, an intermediate of natural α-tocopherol was synthesized from (S)-2-benzyloxy-2-methyl-4-pentenoic acid, which was obtained by the enzymatic hydrolysis of the corresponding racemic methyl ester.
