136057-07-3Relevant academic research and scientific papers
APPLICATION OF 4-AZIDOBENZYL GROUP TO PROTECTION OF HYDROXYL FUNCTIONS
Fukase, Koichi,Hashida, Manabu,Kusumoto, Shoichi
, p. 3557 - 3558 (2007/10/02)
The 4-azidobenzyl ether can be readily formed and cleaved either by direct oxidation with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) or by oxidation after conversion to the 4-aminobenzyl ether or the corresponding iminophosphorane derivative.In the latter two-step cleavage methods the azidobenzyl group is removed in preference to the 4-methoxybenzyl (MPM) group, whereas the MPM group can be selectively removed by the direct DDQ oxidation.
