1361033-75-1Relevant academic research and scientific papers
Highly regioselective copper-catalyzed benzylic C-H amination by N-fluorobenzenesulfonimide
Ni, Zhikun,Zhang, Qian,Xiong, Tao,Zheng, Yiying,Li, Yan,Zhang, Hongwei,Zhang, Jingping,Liu, Qun
supporting information; experimental part, p. 1244 - 1247 (2012/03/09)
Primary target: A practical and effective copper-catalyzed amination strategy for synthesizing various benzylic amines from benzylic hydrocarbons is described (see scheme; DCE=1,2-dichloroethane). Xylene substrates can undergo diamination reactions using this method. The remarkable preference for primary over secondary benzylic C-H bonds has been observed for the first time. Copyright
