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cis-[Fe(η2-phenylhydrazine(-H))(1,2-bis(dimethylphosphino)ethane)2]Cl*tetrahydrofuran is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1362816-45-2

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1362816-45-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1362816-45-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,6,2,8,1 and 6 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1362816-45:
(9*1)+(8*3)+(7*6)+(6*2)+(5*8)+(4*1)+(3*6)+(2*4)+(1*5)=162
162 % 10 = 2
So 1362816-45-2 is a valid CAS Registry Number.

1362816-45-2Relevant academic research and scientific papers

Side-on bound complexes of phenyl- and methyl-diazene

Field, Leslie D.,Li, Hsiu L.,Dalgarno, Scott J.,McIntosh, Ruaraidh D.

, p. 3733 - 3742 (2012)

Treatment of trans-[FeCl2(dmpe)2] with phenylhydrazine and 1 equiv of base afforded the side-on bound phenylhydrazido complex cis-[Fe(η2-NH2NPh)(dmpe)2] +. Further deprotonation of the phenylhydrazido complex afforded the side-on bound phenyldiazene complex cis-[Fe(η2-HN=NPh)(dmpe) 2] as a mixture of diastereomers. Treatment of cis-[RuCl 2(dmpe)2] with phenylhydrazine or methylhydrazine afforded the end-on bound phenylhydrazine or methylhydrazine complexes cis-[RuCl(η1-NH2NHR)(dmpe)2]+ (R = Ph, Me). Treatment of the substituted hydrazine complexes with base afforded the side-on bound phenylhydrazido complex cis-[Ru(η2-NH 2NPh)(dmpe)2]+ as well as the phenyldiazene and methyldiazene complexes cis-[Ru(η2-HN=NR)(dmpe)2] (R = Ph, Me). cis-[RuCl(η1-NH2NHR)(dmpe) 2]+ (R = Ph, Me), cis-[M(η2-NH 2NPh)(dmpe)2]+ (M = Fe, Ru) and cis-[Ru(η2-HN=NPh)(dmpe)2] were characterized structurally by X-ray crystallography. cis-[Ru(η2-HN=NPh)(dmpe) 2] is the first side-on bound phenyldiazene complex to be structurally characterized. In the structure of cis-[Ru(η2-HN= NPh)(dmpe)2], the geometry of the coordinated diazene fragment is significantly nonplanar (CNNH angle 137°) suggesting that the complex is probably better described as a Ru(II) metallodiaziridine than a Ru(0) diazene π-complex.

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