13633-87-9

Basic information

• Product Name: 4-CHLOROPHENYL ACRYLATE
• Synonyms: 4-CHLOROPHENYL ACRYLATE
• CAS NO: 13633-87-9
• Molecular Formula: C₉H₇ClO₂
• Molecular Weight: 182.6
• Product Categories: monomer
• Mol File: 13633-87-9.mol
• Article Data: 9

Chemical Properties

• Melting Point: 101-102 °C
• Boiling Point: 70°C 1mm
• Flash Point: 132°C
• Appearance: /
• Density: 1.212g/cm³
• Vapor Pressure: 0.00678mmHg at 25°C
• Refractive Index: 1.534
• CAS DataBase Reference: 4-CHLOROPHENYL ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-CHLOROPHENYL ACRYLATE(13633-87-9)
• EPA Substance Registry System: 4-CHLOROPHENYL ACRYLATE(13633-87-9)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 13633-87-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H7ClO2/c1-2-9(11)12-8-5-3-7(10)4-6-8/h2-6H,1H2

Upstream product

• 814-68-6 acryloyl chloride 
• 1193-00-6 sodium 4-chlorophenolate 
• 106-48-9 4-chloro-phenol 
• 79-10-7 acrylic acid 
• 86259-99-6 4'-chlorophenyl 3-bromopropionate 

Downstream Products

• 114521-79-8 (1R,2S,4S)-1,4,5,6,7,7-Hexabromo-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 4-chloro-phenyl ester 
• 117928-47-9 1,4,5,6-Tetrabromo-7,7-dimethoxy-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 4-chloro-phenyl ester 
• 79-10-7 acrylic acid 
• 144261-54-1 3-phenyl-3-hydroxy-2-methylene-propanoic acid p-chlorophenyl ester 
• 1620141-46-9 (R)-4-chlorophenyl 4-nitro-4-(phenylsulfonyl)pentanoate 
• 1586777-29-8 C₂₁H₁₅ClN₂O₃ 
• 1210408-78-8 1-(4-chlorophenyl) 2,3,4,5-tetraethyl benzene-1,2,3,4,5-pentacarboxylate 
• 1210408-68-6 1-(4-chlorophenyl) 2,3,4,5-tetramethyl benzene-1,2,3,4,5-pentacarboxylate 

Relevant articles and documents

Acid- And base-switched palladium-catalyzed γ-C(sp3)-H alkylation and alkenylation of neopentylamine

The functionalization of remote unactivated C(sp3)-H and the reaction selectivity are among the core pursuits for transition-metal catalytic system development. Herein, we report Pd-catalyzed γ-C(sp3)-H-selective alkylation and alkenylation with removable 7-azaindole as a directing group. Acid and base were found to be the decisive regulators for the selective alkylation and alkenylation, respectively, on the same single substrate under otherwise the same reaction conditions. Various acrylates were compatible for the formation of C(sp3)-C(sp3) and C(sp3)-C(sp2) bonds. The alkenylation protocol could be further extended to acrylates with natural product units and α,β-unsaturated ketones. The preliminary synthetic manipulation of the alkylation and alkenylation products demonstrates the potential of this strategy for structurally diverse aliphatic chain extension and functionalization. Mechanistic experimental studies showed that the acidic and basic catalytic transformations shared the same six-membered dimer palladacycle.

How much does the hybridization of a carbon atom affect the transmission of the substituent effect on the chemical shift?

1H and 13C NMR spectra of aryl esters of propionic acid, acrylic acid, and propiolic acid were systematically examined to find out the substituent effect on the chemical shift. The values of the chemical shift of the carbonyl carbon showed an inverse correlation with the Hammett ?3 values, and the magnitude of the slope was the largest with the propiolates. The ?± carbons of acrylates and propiolates also showed an inverse correlation with much smaller values of the slopes than those of the carbonyl carbons; but those of the propionates showed absolutely no correlation. However, the ?2 carbons of acrylates and propiolates showed normal correlation with larger values of the slopes. The signs and the magnitudes of the slopes may be understood by the transmission of the substituent electronic effect through bonds as well as through space. The propiolyloxy group also showed a significantly large effect on the 13C chemical shift values of the benzene ring.

An Improved Preparation of 7-Hydroxyindan-1-ones

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