136346-95-7Relevant academic research and scientific papers
Iridium(III)-Catalyzed C-H Functionalization of Triarylphosphine Oxides with Diazo Dicarbonyl Compounds: Synthesis of α-Aryl 1,3-Dicarbonyl Derivatives
Lou, Qin-Xin,Li, Jing-Yu,Yang, Shang-Dong
supporting information, (2021/04/15)
A novel (pentamethylcyclopenta-1,3-dienyl)iridium(III)-catalyzed direct C-H functionalization of triarylphosphine oxides with diazo dicarbonyl compounds through carbene insertion has been developed. This strategy provides a simple and efficient route to t
CONDENSATION OF NITRILES WITH METHYL KETONES AS A METHOD FOR THE SYNTHESIS OF β-AMINOVINYL KETONES
Sosnovskikh, V. Ya.,Ovsyannikov, I. S.
, p. 1801 - 1805 (2007/10/02)
The condensation of nitriles containing aromatic substituents and of trichloroacetonitrile with methyl ketones in the presence of (phenylethylamino)magnesium bromide leads to β-aminovinyl ketones.Acid hydrolysis of the β-aminovinyl ketones gave high yields of the corresponding β-diketones.
