136370-75-7Relevant academic research and scientific papers
Ytterbium Tricyanide, a Highly Efficient Catalyst for the Addition of Cyanotrimethylsilane to Carbonyl Compounds
Matsubara, Seijiro,Takai, Tsutomu,Utimoto, Kiitiro
, p. 1447 - 1450 (1991)
Reaction of cyanotrimethylsilane with various carbonyl compounds was effectively catalyzed by Yb(CN)3 to give the adducts in excellent yields; reaction with substituted cyclohexanones proceeded in a highly stereoselective manner.
[HC(py)3W(NO)2(CO)](SbF6)2 as a Lewis acid precursor in additions of silylated C-nucleophiles to carbonyl compounds
Faller,Gundersen, Lise-Lotte
, p. 2275 - 2278 (2007/10/02)
[HC(py)3W(NO)2(CO)](SbF6)2 is a feasible Lewis acid catalyst precursor for the addition of silylated C-nucleophiles to carbonyl compounds. The O-silylated adducts are easily isolated without aqueous work-up and
