Ytterbium Tricyanide, a Highly Efficient Catalyst for the Addition of Cyanotrimethylsilane to Carbonyl Compounds

DOI: 10.1246/cl.1991.1447

Source and publish data:

Chemistry Letters p. 1447 - 1450 (1991)

Update date:2022-07-30

Topics:

Authors:

Matsubara, Seijiro

Takai, Tsutomu

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1991.1447

Reaction of cyanotrimethylsilane with various carbonyl compounds was effectively catalyzed by Yb(CN)3 to give the adducts in excellent yields; reaction with substituted cyclohexanones proceeded in a highly stereoselective manner.

Full text of DOI:10.1246/cl.1991.1447

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