137144-17-3

Upstream product

• 62835-97-6 β,2-dimethylbenzeneethanol 
• 917-54-4 methyllithium 
• 137144-05-9 (3R,3aR,7aS)-3-Methoxymethyl-3,7a-dimethyl-3a,7a-dihydro-3H-indazole 
• 644-36-0 o-methylphenylacetic acid 
• 50983-21-6 1,4-Cyclohexadien-1-carbonsaeure-methylester 
• 137144-15-1 (rac)-2-(2-methylphenyl)propanoic acid 
• 137144-08-2 ((3R,3aS,7aS)-3-Methoxymethyl-3-methyl-3,3a,4,7-tetrahydro-indazol-7a-yl)-methanol 
• 137144-07-1 (3R,3aS,7aS)-3-Methoxymethyl-3-methyl-3,3a,4,7-tetrahydro-indazole-7a-carboxylic acid methyl ester 
• 137144-09-3 Toluene-4-sulfonic acid (3S,3aR,7aR)-3-methoxymethyl-3-methyl-3,3a,4,7-tetrahydro-indazol-7a-ylmethyl ester 
• 137144-10-6 (3R,3aR,7aS)-3-Methoxymethyl-3,7a-dimethyl-3a,4,7,7a-tetrahydro-3H-indazole 
• 137144-11-7 (3S,3aS,7aR)-5,6-Dibromo-3-methoxymethyl-3,7a-dimethyl-3a,4,5,6,7,7a-hexahydro-3H-indazole 

Relevant academic research and scientific papers

Mechanism of the Cyclopropane "Walk" Rearrangement: Synthesis and Properties of an Optically Active Diazoalkane-Toluene Adduct; a Highly Stereoselective N2 Elimination

The synthesis and the thermal and photochemical behavior of the optically active 2-diazo-1-methoxypropane-toluene adduct 3 are reported.The N2 elimination of 3 occurs with one and the same stereochemical course upon thermolysis as well as direct photolysi