137265-57-7

Upstream product

• 137265-56-6 ((1R,5R)-5-Methoxy-cyclohex-3-enylmethoxymethyl)-benzene 
• 130256-40-5 (R)-5-benzyloxymethyl-2-cyclohexenone 
• 137789-31-2 (1R,5R)-5-Benzyloxymethyl-cyclohex-2-enol 
• 24509-26-0 (R)-2-Allyl-4-methyl-pent-4-en-1-ol 
• 67-56-1 methanol 
• 138124-71-7 t-4-<(benzyloxy)methyl>-r-1,2-epoxycyclohexane 
• 137946-34-0 c-4-<(benzyloxy)methyl>-r-1,2-epoxycyclohexane 
• 74-88-4 methyl iodide 
• 130256-39-2 Acetic acid (1S,3S,5R)-3-benzyloxymethyl-5-hydroxy-cyclohexyl ester 
• 137298-86-3 (4S,5R)-3-((R)-2-Allyl-4-methyl-pent-4-enoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 137298-87-4 ((R)-2-Allyl-4-methyl-pent-4-enyloxymethyl)-benzene 

Downstream Products

• 128684-91-3 (1R,2R,4R)-4-(hydroxymethyl)-2-methoxy-1-<(triisopropylsilyl)oxy>cyclohexane 
• 122948-78-1 (1R,2R,4R)-4-<(E)-2-bromo-1-propen-1-yl>-2-methoxy-1-<(triisopropylsilyl)oxy>cyclohexane 
• 137298-84-1 C₇₄H₁₃₈O₉S₂Si₃ 
• 137298-84-1 C₇₄H₁₃₈O₉S₂Si₃ 
• 109466-73-1 (-)-(1R,2R,4R)-4-hydroxymethyl-2-methoxycyclohexan-1-ol 

Relevant academic research and scientific papers

Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes. Part 14: Regioselectivity of the opening reactions with MeOH of remote O-substituted 1,2-epoxycyclohexanes under gas-phase operating conditions

The regiochemical behavior of cyclohexene oxides bearing a remote O-functionality was determined in the gas-phase in opening reactions with MeOH, using a gaseous acid (D3/+, C(n)H5/+, Me2F+

Regiochemical Control of the Ring-Opening of 1,2-Epoxides by Means of Chelating Processes. 2. Synthesis and Reactions of the cis- and trans-Oxides of 4-cyclohexene, 3-Cyclohexenemethanol, and Methyl 3-Cyclohexenecarboxylate

The synthesis of the diastereoisomeric epoxides cis-1b-d and trans-2b-d and the products of their ring-opening by various nucleophiles are described.The results of the ring-openings of the trans-epoxides 2b-d can be rationalized by combining stereoelectro

Revision of the enantiotoposelective PLE-catalyzed hydrolysis of cis-5-substituted-1,3-diacyloxycyclohexanes

Revision of previous work shows that PLE-catalyzed hydrolysis of 1 leads to the (S)-alcohol 5 and not the (R)-alcohol 3.However the homologue 2 gives the (R)-alcohol 4.

Synthetic studies towards the immunosuppressant FK-506 synthesis of the C10-C34 fragment

The synthesis of the cyclohexyl moiety of FK-506 and its coupling reaction with the C10-C26 fragment to provide an advanced synthetic intermediate(C10-C34) are described.