1372793-96-8

Basic information

• Product Name: (Z)-ethyl 2-diazo-3-(methoxyimino)-3-phenylpropanoate
• Synonyms: (Z)-ethyl 2-diazo-3-(methoxyimino)-3-phenylpropanoate
• CAS NO: 1372793-96-8
• Molecular Weight: 247.254
• Mol File: 1372793-96-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-ethyl 2-diazo-3-(methoxyimino)-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-ethyl 2-diazo-3-(methoxyimino)-3-phenylpropanoate(1372793-96-8)
• EPA Substance Registry System: (Z)-ethyl 2-diazo-3-(methoxyimino)-3-phenylpropanoate(1372793-96-8)

Safety Data

• Hazardous Substances Data: 1372793-96-8(Hazardous Substances Data)

Upstream product

• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 66102-65-6 trans-ethyl 3-(methoxyimino)-3-phenylpropanoate 
• 342626-64-6 ethyl 3-(methoxyimino)-3-phenylpropanoate 

Downstream Products

• 1372794-36-9 ethyl 3-cyano-5-phenyl-1H-pyrrole-2-carboxylate 
• 1372794-23-4 triethyl 5-phenyl-1H-pyrrole-2,3,4-tricarboxylate 
• 65474-26-2 ethyl 2,5-diphenyl-1H-pyrrole-3-carboxylate 
• 38597-58-9 2-phenyl-1H-pyrrole-3-carboxylic acid ethyl ester 

Relevant articles and documents

The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes

Cationic gold complexes of α-oximimino carbenes have been identified to react with weak nucleophiles including enol ethers and nitriles. These findings allowed us to develop the highly efficient synthesis of pyrroles and oxazoles.

NaOH/Et 3N-promoted stereoselective one-pot synthesis of α-Diazo Oxime Ethers via Diazo transfer reaction

For the first time, we have observed a combined effect of two bases NaOH/Et3N to promote the diazo transfer reaction of β-oximino esters. This unusual synergistic effect has been employed to obtain α-diazo oxime ethers directly from β-keto esters by one-p