1374683-07-4Relevant articles and documents
Asymmetric α-oxyacylation of cyclic ketones
Smithen, Deborah A.,Mathews, Christopher J.,Tomkinson, Nicholas C.O.
supporting information; experimental part, p. 3756 - 3762 (2012/06/01)
Reaction of cyclic ketones with chiral N-alkyl-O-acyl hydroxylamines leads to the corresponding α-oxyacylated carbonyl compound in up to 89% ee. The levels of asymmetric induction were influenced by solvent polarity, acid strength and, to a lesser extent,