13765-03-2

Basic information

• Product Name: LITHIUM IODATE
• Synonyms: iodicacid(hio3),lithiumsalt;Iodicacid(HIO3)lithiumsalt;Iodicacid,lithiumsalt;Lithiumiodate(LiIO3);LITHIUM IODATE;LITHIUM IODATE REAGENT;LI(lithium iodate)
• CAS NO: 13765-03-2
• Molecular Formula: ILiO3
• Molecular Weight: 181.84
• EINECS: 237-365-2
• Product Categories: Inorganic Salts;Lithium Salts;LithiumMetal and Ceramic Science;Salts;Synthetic Reagents;Chemical Synthesis;Inorganic Salts;Lithium;Lithium Salts;Materials Science;Metal and Ceramic Science;Synthetic Reagents
• Mol File: 13765-03-2.mol
• Article Data: 6

Chemical Properties

• Melting Point: 50–60℃ [HAW93]
• Appearance: /
• Density: 4.487
• Water Solubility: soluble H2O; insoluble alcohol [HAW93]
• CAS DataBase Reference: LITHIUM IODATE(CAS DataBase Reference)
• NIST Chemistry Reference: LITHIUM IODATE(13765-03-2)
• EPA Substance Registry System: LITHIUM IODATE(13765-03-2)

Safety Data

• Hazard Codes: O,T
• Statements: 61-8-36/37/38
• Safety Statements: 53-17-22-36/37/39-45
• RIDADR: UN 1479 5.1/PG 2
• WGK Germany: 3
• HazardClass: 5.1
• PackingGroup: II
• Hazardous Substances Data: 13765-03-2(Hazardous Substances Data)

Usage

Chemical Properties

-80 mesh with 99.9% purity; has two forms, α and β; white powder(s); oxidizing agent [HAW93] [CER91]

Purification Methods

Crystallise it from water and dry it in a vacuum oven at 60o.

InChI:InChI=1/HIO3.Li/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1

Upstream product

• 10377-51-2 lithium iodide 
• 80937-33-3 oxygen 
• 7782-68-5 iodic acid 
• 554-13-2 lithium carbonate 
• 21111-84-2 lithium metaperiodate 

Downstream Products

• 10377-51-2 lithium iodide 
• 14362-44-8 iodide 
• 1316858-53-3 Bismuth oxide iodate 
• 10043-35-3 sassolite 
• 7553-56-2 iodine 

Related news

LITHIUM IODATE (cas 13765-03-2) planar waveguides by proton implantation09/29/2019

Permanent optical waveguides have been produced by proton implantation in LilO 3 single crystals by using a Van De Graaff accelerator. The effects of the crystal cut and of the implantation parameters on the optical waveguides properties, investigated by dark line mode spectroscopy, are ...detailed

1 2 7 I NQR and spectroscopic investigation of impurity-doped and mixed LITHIUM IODATE (cas 13765-03-2) Li 1 - x H x IO 3 crystals10/01/2019

The 1 2 7 I NQR, IR absorption and Raman spectra of impurity-doped and mixed lithium iodate Li 1 - x H x IO 3 crystals grown from water solutions with different LiIO 3 /HIO 3 ratios were investigated depending on the content of the ...detailed

Structural, electrical, dielectric and optical investigations of LITHIUM IODATE (cas 13765-03-2) single crystals09/27/2019

The crystal structure of α- and β-LiIO 3 at room temperature was examined using X-rays diffraction. Differential thermal analysis (DTA) with different heating rates (5-50K/min) in the range 300-600K was performed. The activation energy of phase transition was calculated by two methods ...detailed

Growth of profiled single crystals of LITHIUM IODATE (cas 13765-03-2) using a shaper from polymer nanoparticles09/26/2019

A possibility of growth of profiled single crystals of α-LiIO3 with a hollow channel using a shaper from polymer nanoparticles is showed. A method of creating the nanoparticles of polystyrene is described.detailed

Relevant articles and documents

Dielectric characterization and ionic conductivity of α-LiIO3 crystals related to the growth conditions

The dielectric response of α-LiIO3 has been studied at room temperature between 20 Hz and 1 MHz with various types of electrodes and compared to the results in the literature. By changing the sample thickness, a relaxation of space charges is clearly identified and the bulk ionic conductivity is deduced from the admittance diagram. Finally a comparison is carried out between chromium doped and undoped crystals obtained from acid and neutral growth solutions.

Electrical conductivity of α-LiIO3 acid type crystals at 1 kHz

The temperature dependence of the electrical conductivity of α-LiIO3 acid type crystals is studied. By applying a very low amplitude electric field at 1 kHz and performing a continuous sampling of measurements, differences, reproducible for all the investigated samples, appeared between the first and subsequent heatings The anomalies occurring during the first heating are attributed mainly to inclusions of mother liquor, HIO3 and Li1-xHxIO3. The 'intrinsic' conductivity is measured after a first annealing at about 470 K; the activation energies are then calculated.

OXIDATION OF ALKALI METAL IODATES IN MOLTEN ALKALI METAL NITRATES

Alkali metal iodates MIO3 (M=Li, Na, K) were oxidized in the presence of hydroxides MOH in molten nitrates MNO3 with oxygen or ozone.The following products were precipitated at variable MOH:MIO3 rations and then separated from the melts and identified after purification with liquid ammonia: Li5IO6, Na4IO5, Na5IO6, K2IO4, K3IO5.Two of these substances, Na4IO5 and K2IO4 contain formally hexavalent iodine and were studied by X-ray powder method, IR spectroscopy and measurements of the magnetic susceptibility.Their thermodynamic stability was also investigated.Periodates Na5IO6 and K3IO5 have been pepared for the first time from a homoge neous mixture by precipitation with an oxidizing agent.